Refinery Wastewater Emissions Tool

Refinery_Wastewater_Emissions_Tool_ICRv2.1.xlsx

NSPS and NESHAP for Petroleum Refineries Sector Residual Risk and Technology Review (New Collection)

Refinery Wastewater Emissions Tool

OMB: 2060-0657

Document [xlsx]
Download: xlsx | pdf

Overview

Introduction
POTW Discharge
Wastewater Collection System
Weir
Oil-Water Separators
DAF
EQ Tanks
Bio. Diff. Aer. Act. Sldg.
Bio. Mech. Aer. Act. Sldg.
Quiescent Unit
Chemical Properties

Sheet 1: Introduction
REFINERY WASTEWATER EMISSION TOOL: ICR VERSION 2.1 (RWETv2.1)







































































































Collection System
































minWindSpd
















0.1 m/s




















































































































































































































The Refinery Wastewater Emissions Tool Version 1.0 (RWET) is an Excel-based model designed to help regulated facilities estimate air emissions from wastewater collection and treatment systems. Separate sheets in RWET represent individual components in a typical wastewater treatment system and can estimate emissions for that particular unit. Effluent concentrations from a particular component can then be used as inputs for the next downstream collection or treatment unit. The calculations are primarily based on those presented in EPA AP-42 but also include updates deemed more accurate in the literature. The equations are presented in Appendix B of the emission protocol document.















Air Emissions










Each sheet is set-up with a series of critical inputs, constants/variables with default values, and outputs. The following procedure should be used to reliably use RWET:


































1.      Determine the critical inputs of the unit listed on the corresponding sheet of RWET and record them on appropriate sheet.



















2.      Determine the influent concentrations of the pollutants of interest and input them into the model.



















3.      Review the default values of the variables and constants and make site-specific adjustments if necessary.



















4.      Review the chemical properties sheet and make any site-specific adjustments if necessary.



















5.      Record the air emissions for reporting and copy the pollutant effluent concentrations as inputs to the next downstream unit.



















6.      Repeat this process for the next downstream unit.




















Sheet 2: POTW Discharge
This sheet is used for facilities that discharge wastewater to a POTW only. Directions: 1) Input (yellow boxes) facility wastewater flow rate and flow rate at the POTW; 2) Input (yellow boxes) constituent concentrations in the facility wastewater. The outputs (green boxes) are the pollutant concentration after dilution in the POTW wastewater. The treatment units of the POTW are then used to estimate air emissions using RWET.



INPUTS VALUE UNITS



Wastewater discharge flow rate (Q) 1.000 m3/s



POTW Wastewater flow rate (QPOTW) 10.000 m3/s










CONSTITUENT DISCHARGE CONCENTRATIONS TO POTW (C0)
CONSTITUENT CONCENTRATIONS AT POTW (C)
Methanol 1.000 g/m3
Methanol 0.091 g/m3
Benzene 1.000 g/m3
Benzene 0.091 g/m3
Carbon disulfide 1.000 g/m3
Carbon disulfide 0.091 g/m3
Methyl ethyl ketone 1.000 g/m3
Methyl ethyl ketone 0.091 g/m3
Naphthalene 1.000 g/m3
Naphthalene 0.091 g/m3
Cumene 0.000 g/m3
Cumene 0.000 g/m3
Ethylbenzene 0.000 g/m3
Ethylbenzene 0.000 g/m3
Styrene 0.000 g/m3
Styrene 0.000 g/m3
1,3-Butadiene 0.000 g/m3
1,3-Butadiene 0.000 g/m3
Ethylene glycol 0.000 g/m3
Ethylene glycol 0.000 g/m3
Methyl isobutyl ketone 0.000 g/m3
Methyl isobutyl ketone 0.000 g/m3
Toluene 0.000 g/m3
Toluene 0.000 g/m3
Phenol 0.000 g/m3
Phenol 0.000 g/m3
n-Hexane 0.000 g/m3
n-Hexane 0.000 g/m3
Cresols (total) 0.000 g/m3
Cresols (total) 0.000 g/m3
Xylenes 0.000 g/m3
Xylenes 0.000 g/m3
Methyl tert-butyl ether 0.000 g/m3
Methyl tert-butyl ether 0.000 g/m3
Biphenyl, 1,1- 0.000 g/m3
Biphenyl, 1,1- 0.000 g/m3
Carbonyl sulfide 0.000 g/m3
Carbonyl sulfide 0.000 g/m3
Dichloroethane, 1,2- 0.000 g/m3
Dichloroethane, 1,2- 0.000 g/m3
Diethanolamine 0.000 g/m3
Diethanolamine 0.000 g/m3
Trimethylpentane, 2,2,4- 0.000 g/m3
Trimethylpentane, 2,2,4- 0.000 g/m3
Compound A 0.000 g/m3
Compound A 0.000 g/m3
Compound B 0.000 g/m3
Compound B 0.000 g/m3
Compound C 0.000 g/m3
Compound C 0.000 g/m3
Butane (VOC Surrogate) 0.000 g/m3
Butane (VOC Surrogate) 0.000 g/m3

Sheet 3: Wastewater Collection System
This sheet is used for wastewater collection systems. Directions: 1) input the number of collection system components for each process drainage area; 2) input the process drainage area point-of-generation concentrations and flow rate (yellow boxes); 3) review the default air emissions control efficiencies and change if necessary; and 4) record the collection system air emissions and wastewater concentrations for downstream process units air emissions calculations (green boxes).




























































































































































Collection System Component Process Drainage Area #1 Process Drainage Area #2 Process Drainage Area #3 Process Drainage Area #4 Process Drainage Area #5 Process Drainage Area #6 Process Drainage Area #7 Process Drainage Area #8 Process Drainage Area #9 Process Drainage Area #10 Process Drainage Area #11 Process Drainage Area #12 Process Drainage Area #13 Process Drainage Area #14 Process Drainage Area #15 Process Drainage Area #16 Process Drainage Area #17 Process Drainage Area #18 Process Drainage Area #19 Process Drainage Area #20



























































Number of uncontrolled drains 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0



























































Number of sealed drains 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0



























































Linear meters of open trench 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0



























































Number of uncontrolled manholes 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0



























































Number of sealed manholes 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0



























































Number of uncontrolled junction boxes 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0



























































Number of controlled junction boxes 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0



























































Number of uncontrolled lift stations 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0



























































Number of controlled lift stations 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0



























































Number of uncontrolled sumps 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0



























































Number of controlled sumps 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0












































































































































Collection System Component Air Emissions Control Control Efficiency, % Default Control Efficiency, %













































































Drain water seal 95 95













































































Manhole seal 95 95













































































Junction box water seal 95 95













































































Lift station control (e.g., carbon adsportion) 95 95













































































Sump control (e.g., carbon adsorption) 95 95
















































































































































































































































Process Drainage Area #1 Process Drainage Area #2 Process Drainage Area #3 Process Drainage Area #4 Process Drainage Area #5 Process Drainage Area #6 Process Drainage Area #7 Process Drainage Area #8 Process Drainage Area #9 Process Drainage Area #10 Process Drainage Area #11 Process Drainage Area #12 Process Drainage Area #13 Process Drainage Area #14 Process Drainage Area #15 Process Drainage Area #16 Process Drainage Area #17 Process Drainage Area #18 Process Drainage Area #19 Process Drainage Area #20
Wastewater flow rate (Q) 1.000 m3/s

0.000 m3/s

0.000 m3/s

0.000 m3/s

0.000 m3/s

0.000 m3/s

0.000 m3/s

0.000 m3/s

0.000 m3/s

0.000 m3/s

0.000 m3/s

0.000 m3/s

0.000 m3/s

0.000 m3/s

0.000 m3/s

0.000 m3/s

0.000 m3/s

0.000 m3/s

0.000 m3/s

0.000 m3/s

Compound Name POG Concentration Units Air Emissions Units POG Concentration Units Air Emissions Units POG Concentration Units Air Emissions Units POG Concentration Units Air Emissions Units POG Concentration Units Air Emissions Units POG Concentration Units Air Emissions Units POG Concentration Units Air Emissions Units POG Concentration Units Air Emissions Units POG Concentration Units Air Emissions Units POG Concentration Units Air Emissions Units POG Concentration Units Air Emissions Units POG Concentration Units Air Emissions Units POG Concentration Units Air Emissions Units POG Concentration Units Air Emissions Units POG Concentration Units Air Emissions Units POG Concentration Units Air Emissions Units POG Concentration Units Air Emissions Units POG Concentration Units Air Emissions Units POG Concentration Units Air Emissions Units POG Concentration Units Air Emissions Units
Methanol 1.0000 g/m3 0 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s
Benzene 1.0000 g/m3 0 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s
Carbon disulfide 1.0000 g/m3 0 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s
Methyl ethyl ketone 1.0000 g/m3 0 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s
Naphthalene 1.0000 g/m3 0 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s
Cumene 1.0000 g/m3 0 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s
Ethylbenzene 1.0000 g/m3 0 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s
Styrene 1.0000 g/m3 0 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s
1,3-Butadiene 1.0000 g/m3 0 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s
Ethylene glycol 1.0000 g/m3 0 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s
Methyl isobutyl ketone 1.0000 g/m3 0 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s
Toluene 1.0000 g/m3 0 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s
Phenol 1.0000 g/m3 0 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s
n-Hexane 1.0000 g/m3 0 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s
Cresols (total) 1.0000 g/m3 0 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s
Xylenes 1.0000 g/m3 0 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s
Methyl tert-butyl ether 1.0000 g/m3 0 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s
Biphenyl, 1,1- 1.0000 g/m3 0 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s
Carbonyl sulfide 1.0000 g/m3 0 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s
Dichloroethane, 1,2- 1.0000 g/m3 0 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s
Diethanolamine 1.0000 g/m3 0 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s
Trimethylpentane, 2,2,4- 1.0000 g/m3 0 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s
Compound A 1.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s
Compound B 1.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s
Compound C 1.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s 0.0000 g/m3 Err:502 g/s
n-Butane (VOC Surrogate) 1.0000 g/m3 0 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s 0.0000 g/m3 0.000E+00 g/s





















































































































































































































































































































































































































OUTPUTS









































































Compound Name Total Emissions Units Collection System Effluent Concentration Units POG Total Load Units









































































Methanol 0.000000 g/s 1.00000 g/m3 1.0000 g/s









































































Benzene 0.000000 g/s 1.00000 g/m3 1.0000 g/s









































































Carbon disulfide 0.000000 g/s 1.00000 g/m3 1.0000 g/s









































































Methyl ethyl ketone 0.000000 g/s 1.00000 g/m3 1.0000 g/s









































































Naphthalene 0.000000 g/s 1.00000 g/m3 1.0000 g/s









































































Cumene 0.000000 g/s 1.00000 g/m3 1.0000 g/s









































































Ethylbenzene 0.000000 g/s 1.00000 g/m3 1.0000 g/s









































































Styrene 0.000000 g/s 1.00000 g/m3 1.0000 g/s









































































1,3-Butadiene 0.000000 g/s 1.00000 g/m3 1.0000 g/s









































































Ethylene glycol 0.000000 g/s 1.00000 g/m3 1.0000 g/s









































































Methyl isobutyl ketone 0.000000 g/s 1.00000 g/m3 1.0000 g/s









































































Toluene 0.000000 g/s 1.00000 g/m3 1.0000 g/s









































































Phenol 0.000000 g/s 1.00000 g/m3 1.0000 g/s









































































n-Hexane 0.000000 g/s 1.00000 g/m3 1.0000 g/s









































































Cresols (total) 0.000000 g/s 1.00000 g/m3 1.0000 g/s









































































Xylenes 0.000000 g/s 1.00000 g/m3 1.0000 g/s









































































Methyl tert-butyl ether 0.000000 g/s 1.00000 g/m3 1.0000 g/s









































































Biphenyl, 1,1- 0.000000 g/s 1.00000 g/m3 1.0000 g/s









































































Carbonyl sulfide 0.000000 g/s 1.00000 g/m3 1.0000 g/s









































































Dichloroethane, 1,2- 0.000000 g/s 1.00000 g/m3 1.0000 g/s









































































Diethanolamine 0.000000 g/s 1.00000 g/m3 1.0000 g/s









































































Trimethylpentane, 2,2,4- 0.000000 g/s 1.00000 g/m3 1.0000 g/s









































































Compound A Err:502 g/s Err:502 g/m3 1.0000 g/s









































































Compound B Err:502 g/s Err:502 g/m3 1.0000 g/s









































































Compound C Err:502 g/s Err:502 g/m3 1.0000 g/s









































































n-Butane (VOC Surrogate) 0.000000 g/s 1.00000 g/m3 1.0000 g/s















































































































































































































































































































































































































































































































































































Compound Name fe, Drains fe, Sealed Drains fe, Trenches fe, Manholes fe, Sealed Manholes fe, Junction Boxes fe, Controlled Junction Boxes fe, Lift Stations fe, Controlled Lift Stations fe, Sumps fe, Controlled Sumps




































































Methanol 0.000E+00 0.000E+00 4.298E-03 0.000E+00 0.000E+00 1.245E-02 6.223E-04 3.253E-02 1.626E-03 2.080E-03 1.040E-04




































































Benzene 2.263E-01 1.131E-02 3.986E-02 5.690E-02 2.845E-03 8.712E-02 4.356E-03 2.544E-01 1.272E-02 4.925E-03 2.462E-04




































































Carbon disulfide 2.854E-01 1.427E-02 4.830E-02 7.211E-02 3.605E-03 1.049E-01 5.243E-03 3.071E-01 1.536E-02 5.600E-03 2.800E-04




































































Methyl ethyl ketone 6.518E-02 3.259E-03 1.684E-02 1.547E-02 7.736E-04 3.878E-02 1.939E-03 1.108E-01 5.540E-03 3.083E-03 1.542E-04




































































Naphthalene 1.407E-01 7.033E-03 2.762E-02 3.488E-02 1.744E-03 6.143E-02 3.071E-03 1.781E-01 8.904E-03 3.946E-03 1.973E-04




































































Cumene 2.600E-01 1.300E-02 4.467E-02 6.556E-02 3.278E-03 9.722E-02 4.861E-03 2.844E-01 1.422E-02 5.309E-03 2.655E-04




































































Ethylbenzene 2.384E-01 1.192E-02 4.158E-02 6.001E-02 3.000E-03 9.074E-02 4.537E-03 2.652E-01 1.326E-02 5.063E-03 2.531E-04




































































Styrene 2.015E-01 1.008E-02 3.632E-02 5.053E-02 2.527E-03 7.969E-02 3.985E-03 2.323E-01 1.162E-02 4.642E-03 2.321E-04




































































1,3-Butadiene 3.166E-01 1.583E-02 5.275E-02 8.012E-02 4.006E-03 1.142E-01 5.710E-03 3.349E-01 1.674E-02 5.956E-03 2.978E-04




































































Ethylene glycol 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00




































































Methyl isobutyl ketone 9.682E-02 4.841E-03 2.136E-02 2.361E-02 1.180E-03 4.828E-02 2.414E-03 1.390E-01 6.950E-03 3.445E-03 1.722E-04




































































Toluene 2.324E-01 1.162E-02 4.073E-02 5.847E-02 2.923E-03 8.895E-02 4.447E-03 2.598E-01 1.299E-02 4.994E-03 2.497E-04




































































Phenol 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 1.104E-03 5.521E-05




































































n-Hexane 3.343E-01 1.671E-02 5.528E-02 8.467E-02 4.233E-03 1.195E-01 5.976E-03 3.507E-01 1.753E-02 6.159E-03 3.079E-04




































































Cresols (total) 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 1.603E-03 8.013E-05 3.078E-04 1.539E-05 1.667E-03 8.334E-05




































































Xylenes 2.291E-01 1.145E-02 4.025E-02 5.762E-02 2.881E-03 8.795E-02 4.398E-03 2.569E-01 1.284E-02 4.956E-03 2.478E-04




































































Methyl tert-butyl ether 1.455E-01 7.276E-03 2.832E-02 3.613E-02 1.807E-03 6.289E-02 3.144E-03 1.824E-01 9.121E-03 4.001E-03 2.001E-04




































































Biphenyl, 1,1- 1.216E-01 6.079E-03 2.490E-02 2.997E-02 1.499E-03 5.570E-02 2.785E-03 1.611E-01 8.053E-03 3.728E-03 1.864E-04




































































Carbonyl sulfide 3.025E-01 1.512E-02 5.074E-02 7.649E-02 3.825E-03 1.100E-01 5.499E-03 3.223E-01 1.612E-02 5.795E-03 2.898E-04




































































Dichloroethane, 1,2- 1.779E-01 8.895E-03 3.294E-02 4.446E-02 2.223E-03 7.260E-02 3.630E-03 2.113E-01 1.056E-02 4.371E-03 2.186E-04




































































Diethanolamine 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00




































































Trimethylpentane, 2,2,4- 4.467E-01 2.233E-02 7.134E-02 1.136E-01 5.679E-03 1.532E-01 7.662E-03 4.509E-01 2.254E-02 7.443E-03 3.722E-04




































































Compound A Err:502 Err:502 Err:502 Err:502 Err:502 Err:502 Err:502 Err:502 Err:502 Err:502 Err:502




































































Compound B Err:502 Err:502 Err:502 Err:502 Err:502 Err:502 Err:502 Err:502 Err:502 Err:502 Err:502




































































Compound C Err:502 Err:502 Err:502 Err:502 Err:502 Err:502 Err:502 Err:502 Err:502 Err:502 Err:502




































































n-Butane (VOC Surrogate) 4.061E-01 2.031E-02 6.554E-02 1.031E-01 5.157E-03 1.411E-01 7.053E-03 4.147E-01 2.073E-02 6.979E-03 3.490E-04




































































Sheet 4: Weir
This sheet is used for uncovered primary weirs and uncovered weirs of oil-water separators. Directions: 1) fill-in the input data (yellow boxes); review default variables and constant (yellow boxes) and change if necessary; 2) record air emissions (green boxes); and 3) record effluent concentrations (light blue boxes) for downstream process unit emission calculations.













CRITICAL INPUTS VALUE UNITS
DEFAULT VARIABLES / CONSTANTS VALUE UNITS DEFAULT VALUE
AIR EMISSIONS VALUE UNITS EFFLUENT WATER CONCENTRATION UNITS




Weir height, h 1.524 m
Diffusivity of oxygen in water, DO2,w 2.40E-05 cm2/s 2.40E-05
Methanol 0.000000 g/s 0.000000 g/m3




Wastewater flow rate, Q 1 m3/s
Universal gas constant (R ) 8.21E-05 atm-m3/gmol-K 8.21E-05
Benzene 0.000000 g/s 0.000000 g/m3




Length of weir, l 3 m
Fraction of volume that is oil (FO) 0.001 dimensionless 0.001
Carbon disulfide 0.000000 g/s 0.000000 g/m3




Tail water depth, z 0.1 m





Methyl ethyl ketone 0.000000 g/s 0.000000 g/m3




Temperature (T) 25 deg. C





Naphthalene 0.000000 g/s 0.000000 g/m3













Cumene 0.000000 g/s 0.000000 g/m3













Ethylbenzene 0.000000 g/s 0.000000 g/m3













Styrene 0.000000 g/s 0.000000 g/m3













1,3-Butadiene 0.000000 g/s 0.000000 g/m3













Ethylene glycol 0.000000 g/s 0.000000 g/m3













Methyl isobutyl ketone 0.000000 g/s 0.000000 g/m3












Toluene 0.000000 g/s 0.000000 g/m3













Phenol 0.000000 g/s 0.000000 g/m3













n-Hexane 0.000000 g/s 0.000000 g/m3













Cresols (total) 0.000000 g/s 0.000000 g/m3




CONSTITUENT INFLUENT CONCENTRATIONS (C0)





Xylenes 0.000000 g/s 0.000000 g/m3




Methanol 0.0000 g/m3





Methyl tert-butyl ether 0.000000 g/s 0.000000 g/m3




Benzene 0.0000 g/m3





Biphenyl, 1,1- 0.000000 g/s 0.000000 g/m3




Carbon disulfide 0.0000 g/m3





Carbonyl sulfide 0.000000 g/s 0.000000 g/m3




Methyl ethyl ketone 0.0000 g/m3





Dichloroethane, 1,2- 0.000000 g/s 0.000000 g/m3




Naphthalene 0.0000 g/m3





Diethanolamine 0.000000 g/s 0.000000 g/m3




Cumene 0.0000 g/m3





Trimethylpentane, 2,2,4- 0.000000 g/s 0.000000 g/m3




Ethylbenzene 0.0000 g/m3





Compound A #DIV/0! g/s #DIV/0! g/m3




Styrene 0.0000 g/m3





Compound B #DIV/0! g/s #DIV/0! g/m3




1,3-Butadiene 0.0000 g/m3





Compound C #DIV/0! g/s #DIV/0! g/m3




Ethylene glycol 0.0000 g/m3





n-Butane (VOC Surrogate) 0.000000 g/s 0.000000 g/m3




Methyl isobutyl ketone 0.0000 g/m3















Toluene 0.0000 g/m3















Phenol 0.0000 g/m3















n-Hexane 0.0000 g/m3















Cresols (total) 0.0000 g/m3















Xylenes 0.0000 g/m3















Methyl tert-butyl ether 0.0000 g/m3















Biphenyl, 1,1- 0.0000 g/m3















Carbonyl sulfide 0.0000 g/m3















Dichloroethane, 1,2- 0.0000 g/m3















Diethanolamine 0.0000 g/m3






q 1200






Trimethylpentane, 2,2,4- 0.0000 g/m3






ln( r) 0.311813 (Nakasone)





Compound A 0.0000 g/m3






ln( r)* 2.23931627174719 (Pincince)





Compound B 0.0000 g/m3















Compound C 0.0000 g/m3















n-Butane (VOC Surrogate) 0.0000 g/m3
























INTERMEDIATE OUTPUTS Keq kl kg Ko fair kl Pincince Ko Pincince fair Pincince Emissions, Pincince









Methanol 1.859E-04 5.30E-02 7.1094E-02 1.32116456501436E-05 6.04018196490586E-05 3.81E-01 1.32144786113133E-05 6.04147711651404E-05 0









Benzene 2.279E-01 3.78E-02 5.0000E-02 0.00875443149447 0.039234830844001 2.71E-01 0.010936872419689 0.048773791317848 0









Carbon disulfide 1.235E+00 3.83E-02 5.5828E-02 0.024607690712482 0.106408337883845 2.75E-01 0.055109868267924 0.222725973026109 0









Methyl ethyl ketone 2.284E-03 3.78E-02 4.7261E-02 0.000107621065152 0.000491922476321 2.71E-01 0.00010788572171 0.00049313189014 0









Naphthalene 1.973E-02 3.17E-02 3.8404E-02 0.000740061366612 0.003377842777741 2.27E-01 0.000755261780732 0.003447101916886 0









Cumene 5.965E-01 3.05E-02 4.9247E-02 0.014969486927003 0.066150972144569 2.19E-01 0.0259028847521 0.11168421821552 0









Ethylbenzene 3.219E-01 3.25E-02 4.4994E-02 0.010017335976239 0.044766303521694 2.33E-01 0.013637578643637 0.060446963192607 0









Styrene 1.123E-01 3.30E-02 4.3395E-02 0.004248183963221 0.019235291765728 2.37E-01 0.004777061838239 0.021603945013611 0









1,3-Butadiene 3.007E+00 4.03E-02 9.9335E-02 0.035480314786952 0.14974247024713 2.89E-01 0.146919406015522 0.489168518159871 0









Ethylene glycol 7.354E-08 4.80E-02 7.1911E-02 5.28800611258758E-09 2.41767637021439E-08 3.45E-01 5.28800661392479E-09 2.417676592259E-08 0









Methyl isobutyl ketone 5.639E-03 3.25E-02 4.4994E-02 0.000251753133248 0.001150353161149 2.33E-01 0.000253443983101 0.001158074803951 0









Toluene 2.713E-01 3.46E-02 4.9624E-02 0.00969431921554 0.043354541017665 2.49E-01 0.012770266713343 0.056713909881379 0









Phenol 1.622E-05 3.60E-02 4.7723E-02 7.73983623309223E-07 3.53864686475358E-06 2.58E-01 7.73997962838088E-07 3.53871242486647E-06 0









n-Hexane 4.984E+00 3.24E-02 8.5959E-02 0.030120821124506 0.128650739170907 2.33E-01 0.150784061662439 0.498115231229034 0









Cresols (total) 6.618E-05 3.65E-02 4.2747E-02 2.82886391261064E-06 1.29334821702409E-05 2.62E-01 2.82905274868645E-06 1.29343455176345E-05 0









Xylenes 2.468E-01 3.66E-02 4.3556E-02 0.008308394581162 0.037273561802892 2.63E-01 0.0103272399481 0.046118797570162 0









Methyl tert-butyl ether 2.268E-02 3.95E-02 5.5260E-02 0.001214689314879 0.005538167043381 2.84E-01 0.001247697386383 0.005688232841716 0









Biphenyl, 1,1- 1.144E-02 3.36E-02 2.9910E-02 0.000338687760933 0.001547282165728 2.41E-01 0.000341654643111 0.00156082567095 0









Carbonyl sulfide 2.010E+00 4.55E-02 7.4707E-02 0.034921495202817 0.147567350161423 3.27E-01 0.102883674529689 0.37523778644461 0









Dichloroethane, 1,2- 5.719E-02 3.80E-02 5.5828E-02 0.002945626224436 0.013377123357331 2.73E-01 0.003156121698581 0.014326177966788 0









Diethanolamine 1.581E-09 3.78E-02 4.3153E-02 6.82248185319784E-11 3.11923820106585E-10 2.71E-01 6.82248186380762E-11 3.11923820106585E-10 0









Trimethylpentane, 2,2,4- 1.238E+02 2.91E-02 4.4318E-02 0.028908049485219 0.123805869332288 2.09E-01 0.201056577625858 0.601174249454654 0









Compound A 0.000E+00 0.00E+00 0.0000E+00 #DIV/0! #DIV/0! 0.00E+00 #DIV/0! #DIV/0! #DIV/0!









Compound B 0.000E+00 0.00E+00 0.0000E+00 #DIV/0! #DIV/0! 0.00E+00 #DIV/0! #DIV/0! #DIV/0!









Compound C 0.000E+00 0.00E+00 0.0000E+00 #DIV/0! #DIV/0! 0.00E+00 #DIV/0! #DIV/0! #DIV/0!









n-Butane (VOC Surrogate) 3.881E+01 3.90E-02 5.4114E-02 0.038311225587883 0.160676377984076 2.80E-01 0.24725418158924 0.677110822460545 0






















































































































Pollutant Influent load, g/s Effluent load, g/s Air emission load, g/s % Load with effluent % Load air emitted Mass balance check











Methanol 0 0.000 0.00000 #DIV/0! #DIV/0! #DIV/0!











Benzene 0 0.000 0.00000 #DIV/0! #DIV/0! #DIV/0!











Carbon disulfide 0 0.000 0.00000 #DIV/0! #DIV/0! #DIV/0!











Methyl ethyl ketone 0 0.000 0.00000 #DIV/0! #DIV/0! #DIV/0!











Naphthalene 0 0.000 0.00000 #DIV/0! #DIV/0! #DIV/0!











Cumene 0 0.000 0.00000 #DIV/0! #DIV/0! #DIV/0!











Ethylbenzene 0 0.000 0.00000 #DIV/0! #DIV/0! #DIV/0!











Styrene 0 0.000 0.00000 #DIV/0! #DIV/0! #DIV/0!











1,3-Butadiene 0 0.000 0.00000 #DIV/0! #DIV/0! #DIV/0!











Ethylene glycol 0 0.000 0.00000 #DIV/0! #DIV/0! #DIV/0!











Methyl isobutyl ketone 0 0.000 0.00000 #DIV/0! #DIV/0! #DIV/0!











Toluene 0 0.000 0.00000 #DIV/0! #DIV/0! #DIV/0!











Phenol 0 0.000 0.00000 #DIV/0! #DIV/0! #DIV/0!











n-Hexane 0 0.000 0.00000 #DIV/0! #DIV/0! #DIV/0!











Cresols (total) 0 0.000 0.00000 #DIV/0! #DIV/0! #DIV/0!











Xylenes 0 0.000 0.00000 #DIV/0! #DIV/0! #DIV/0!











Methyl tert-butyl ether 0 0.000 0.00000 #DIV/0! #DIV/0! #DIV/0!











Biphenyl, 1,1- 0 0.000 0.00000 #DIV/0! #DIV/0! #DIV/0!











Carbonyl sulfide 0 0.000 0.00000 #DIV/0! #DIV/0! #DIV/0!











Dichloroethane, 1,2- 0 0.000 0.00000 #DIV/0! #DIV/0! #DIV/0!











Diethanolamine 0 0.000 0.00000 #DIV/0! #DIV/0! #DIV/0!











Trimethylpentane, 2,2,4- 0 0.000 0.00000 #DIV/0! #DIV/0! #DIV/0!











Compound A 0 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!











Compound B 0 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!











Compound C 0 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!











n-Butane (VOC Surrogate) 0 0.000 0.00000 #DIV/0! #DIV/0! #DIV/0!


Sheet 5: Oil-Water Separators
This sheet is used for uncovered oil-water separators only. Directions: 1) fill-in the input data (yellow boxes); review default variables and constant (yellow boxes) and change if necessary; 2) record air emissions (green boxes); and 3) record effluent concentrations (light blue boxes) for downstream process unit emission calculations.








CRITICAL INPUTS VALUE UNITS
DEFAULT VARIABLES / CONSTANTS VALUE UNITS DEFAULT VALUE
UNCONTROLLED AIR EMISSIONS VALUE UNITS EFFLUENT WATER CONCENTRATION UNITS

Surface area (A) 200.0 m2
Viscosity of air (ma) 0.000181 g/cm-s 0.000181
Methanol 0.000161 g/s 1.000806 g/m3

Total pressure (Po) 1.0 atm
Density of air (ρa) 0.0012 g/cm3 0.0012
Benzene 0.084980 g/s 0.881915 g/m3

Wastewater flow rate (Q) 1.000 m3/s
Molecular weight of oil (MWoil) 282 g/g-mol 282
Carbon disulfide 0.083126 g/s 0.909918 g/m3

Windspeed (U10) 4.413 m/s
Molecular weight of air (MWair) 29 g/g-mol 29
Methyl ethyl ketone 0.001339 g/s 0.999095 g/m3





Density of oil (ρoil) 0.92 g/cm3 0.92
Naphthalene 0.001190 g/s 0.303964 g/m3





Flow of oil (Qoil) [default = 0.001*Q] 0.001 m3/s 0.001
Cumene 0.000000 g/s 0.000000 g/m3





Fraction of volume that is oil (FO) 0.001 dimensionless 0.001
Ethylbenzene 0.000000 g/s 0.000000 g/m3

CONSTITUENT INFLUENT CONCENTRATIONS (C0)
Oil layer thickness (Olayer) 1 cm 1
Styrene 0.000000 g/s 0.000000 g/m3

Methanol 1.000 g/m3





1,3-Butadiene 0.000000 g/s 0.000000 g/m3

Benzene 1.000 g/m3





Ethylene glycol 0.000000 g/s 0.000000 g/m3

Carbon disulfide 1.000 g/m3





Methyl isobutyl ketone 0.000000 g/s 0.000000 g/m3

Methyl ethyl ketone 1.000 g/m3





Toluene 0.000000 g/s 0.000000 g/m3

Naphthalene 1.000 g/m3





Phenol 0.000000 g/s 0.000000 g/m3

Cumene 0.000 g/m3





n-Hexane 0.000000 g/s 0.000000 g/m3

Ethylbenzene 0.000 g/m3





Cresols (total) 0.000000 g/s 0.000000 g/m3

Styrene 0.000 g/m3





Xylenes 0.000000 g/s 0.000000 g/m3

1,3-Butadiene 0.000 g/m3





Methyl tert-butyl ether 0.000000 g/s 0.000000 g/m3

Ethylene glycol 0.000 g/m3





Biphenyl, 1,1- 0.000000 g/s 0.000000 g/m3

Methyl isobutyl ketone 0.000 g/m3





Carbonyl sulfide 0.000000 g/s 0.000000 g/m3

Toluene 0.000 g/m3





Dichloroethane, 1,2- 0.000000 g/s 0.000000 g/m3

Phenol 0.000 g/m3





Diethanolamine 0.000000 g/s 0.000000 g/m3

n-Hexane 0.000 g/m3





Trimethylpentane, 2,2,4- 0.000000 g/s 0.000000 g/m3

Cresols (total) 0.000 g/m3





Compound A #DIV/0! g/s #DIV/0! g/m3

Xylenes 0.000 g/m3





Compound B #DIV/0! g/s #DIV/0! g/m3

Methyl tert-butyl ether 0.000 g/m3





Compound C #DIV/0! g/s #DIV/0! g/m3

Biphenyl, 1,1- 0.000 g/m3





n-Butane (VOC Surrogate) 0.000000 g/s 0.000000 g/m3

Carbonyl sulfide 0.000 g/m3












Dichloroethane, 1,2- 0.000 g/m3












Diethanolamine 0.000 g/m3












Trimethylpentane, 2,2,4- 0.000 g/m3












Compound A 0.000 g/m3












Compound B 0.000 g/m3





Windspeed (U10) 4.413 m/s



Compound C 0.000 g/m3












n-Butane (VOC Surrogate) 0.000 g/m3





















INTERMEDIATE OUTPUTS ScG kg,q, m/s Keqoil Koil, m/s Cooil, g/m3 CL,oil , g/m3









Methanol 1.006E+00 1.127E-02 2.103E-03 2.370E-05 1.951E-01 3.399E-02









Benzene 1.714E+00 7.885E-03 1.585E-03 1.250E-05 1.190E+02 3.399E+01









Carbon disulfide 1.450E+00 8.819E-03 5.991E-03 5.284E-05 9.099E+01 7.866E+00









Methyl ethyl ketone 1.867E+00 7.447E-03 1.590E-03 1.184E-05 1.904E+00 5.651E-01









Naphthalene 2.556E+00 6.032E-03 1.419E-06 8.557E-09 6.963E+02 6.952E+02









Cumene 1.754E+00 7.765E-03 7.510E-05 5.831E-07 0.000E+00 0.000E+00









Ethylbenzene 2.011E+00 7.084E-03 1.602E-04 1.135E-06 0.000E+00 0.000E+00









Styrene 2.124E+00 6.829E-03 1.021E-04 6.975E-07 0.000E+00 0.000E+00









1,3-Butadiene 6.058E-01 1.583E-02 3.521E-02 5.574E-04 0.000E+00 0.000E+00









Ethylene glycol 9.883E-01 1.140E-02 2.103E-06 2.398E-08 0.000E+00 0.000E+00









Methyl isobutyl ketone 2.011E+00 7.084E-03 3.321E-04 2.353E-06 0.000E+00 0.000E+00









Toluene 1.734E+00 7.825E-03 4.740E-04 3.709E-06 0.000E+00 0.000E+00









Phenol 1.839E+00 7.521E-03 4.606E-06 3.464E-08 0.000E+00 0.000E+00









n-Hexane 7.542E-01 1.367E-02 2.520E-03 3.444E-05 0.000E+00 0.000E+00









Cresols (total) 2.173E+00 6.725E-03 5.007E-06 3.367E-08 0.000E+00 0.000E+00









Xylenes 2.113E+00 6.855E-03 1.342E-04 9.200E-07 0.000E+00 0.000E+00









Methyl tert-butyl ether 1.473E+00 8.728E-03 3.103E-03 2.709E-05 0.000E+00 0.000E+00









Biphenyl, 1,1- 3.733E+00 4.680E-03 1.609E-07 7.530E-10 0.000E+00 0.000E+00









Carbonyl sulfide 9.328E-01 1.185E-02 1.571E-01 1.862E-03 0.000E+00 0.000E+00









Dichloroethane, 1,2- 1.450E+00 8.819E-03 1.327E-03 1.170E-05 0.000E+00 0.000E+00









Diethanolamine 2.143E+00 6.790E-03 4.640E-09 3.150E-11 0.000E+00 0.000E+00









Trimethylpentane, 2,2,4- 2.058E+00 6.976E-03 8.206E-04 5.725E-06 0.000E+00 0.000E+00









Compound A #DIV/0! #DIV/0! 0.000E+00 #DIV/0! 0.000E+00 #DIV/0!









Compound B #DIV/0! #DIV/0! 0.000E+00 #DIV/0! 0.000E+00 #DIV/0!









Compound C #DIV/0! #DIV/0! 0.000E+00 #DIV/0! 0.000E+00 #DIV/0!









n-Butane (VOC Surrogate) 1.520E+00 8.544E-03 3.037E-02 2.595E-04 0.000E+00 0.000E+00









































































































QUALITY CONTROL CHECKS









Pollutant Influent load, g/s Effluent load, g/s Air emission load, g/s % Load with effluent % Load air emitted









Methanol 1.0000 1.001 0.000 100 0









Benzene 1.0000 0.882 0.085 88 8









Carbon disulfide 1.0000 0.910 0.083 91 8









Methyl ethyl ketone 1.0000 0.999 0.001 100 0









Naphthalene 1.0000 0.304 0.001 30 0









Cumene 0.0000 0.000 0.000 #DIV/0! #DIV/0!









Ethylbenzene 0.0000 0.000 0.000 #DIV/0! #DIV/0!









Styrene 0.0000 0.000 0.000 #DIV/0! #DIV/0!









1,3-Butadiene 0.0000 0.000 0.000 #DIV/0! #DIV/0!









Ethylene glycol 0.0000 0.000 0.000 #DIV/0! #DIV/0!









Methyl isobutyl ketone 0.0000 0.000 0.000 #DIV/0! #DIV/0!









Toluene 0.0000 0.000 0.000 #DIV/0! #DIV/0!









Phenol 0.0000 0.000 0.000 #DIV/0! #DIV/0!









n-Hexane 0.0000 0.000 0.000 #DIV/0! #DIV/0!









Cresols (total) 0.0000 0.000 0.000 #DIV/0! #DIV/0!









Xylenes 0.0000 0.000 0.000 #DIV/0! #DIV/0!









Methyl tert-butyl ether 0.0000 0.000 0.000 #DIV/0! #DIV/0!









Biphenyl, 1,1- 0.0000 0.000 0.000 #DIV/0! #DIV/0!









Carbonyl sulfide 0.0000 0.000 0.000 #DIV/0! #DIV/0!









Dichloroethane, 1,2- 0.0000 0.000 0.000 #DIV/0! #DIV/0!









Diethanolamine 0.0000 0.000 0.000 #DIV/0! #DIV/0!









Trimethylpentane, 2,2,4- 0.0000 0.000 0.000 #DIV/0! #DIV/0!









Compound A 0.0000 #DIV/0! #DIV/0! #DIV/0! #DIV/0!









Compound B 0.0000 #DIV/0! #DIV/0! #DIV/0! #DIV/0!









Compound C 0.0000 #DIV/0! #DIV/0! #DIV/0! #DIV/0!









n-Butane (VOC Surrogate) 0.0000 0.000 0.000 #DIV/0! #DIV/0!

Sheet 6: DAF
This sheet is used for uncovered dissolved air floatation (DAF) units only. Directions: 1) fill-in the input data (yellow boxes); review default variables and constant (yellow boxes) and change if necessary; 2) record air emissions (green boxes); and 3) record effluent concentrations (light blue boxes) for downstream process unit emission calculations.













CRITICAL INPUTS VALUE UNITS
DEFAULT VARIABLES / CONSTANTS VALUE UNITS DEFAULT VALUE
AIR EMISSIONS VALUE UNITS EFFLUENT WATER CONCENTRATION UNITS




Surface area (A) 200 m2
Viscosity of water (mL) 0.00893 g/cm-s 0.00893
Methanol 0.000544 g/s 0.972818 g/m3




Temperature (T) 0.5 deg. C
Density of water (ρL) 1 g/cm3 1
Benzene 0.018516 g/s 0.074175 g/m3




Total pressure (Po) 1 atm
Universal gas constant (R ) 8.21E-05 atm-m3/gmol-K 8.21E-05
Carbon disulfide 0.019707 g/s 0.014635 g/m3




Wastewater flow rate (Q) 0.02 m3/s
Viscosity of air (ma) 0.000181 g/cm-s 0.000181
Methyl ethyl ketone 0.002943 g/s 0.852866 g/m3




Wastewater depth (D) 3 m
Density of air (ρa) 0.0012 g/cm3 0.0012
Naphthalene 0.010613 g/s 0.469366 g/m3




Diffused air flow rate (Qa) 1 m3/s
Diffusivity of ether in water (Dether) 8.50E-06 cm2/sec 8.50E-06
Cumene 0.019404 g/s 0.029807 g/m3




Windspeed (U10) 4.413 m/s





Ethylbenzene 0.018925 g/s 0.053775 g/m3













Styrene 0.000000 g/s 0.000000 g/m3




CONSTITUENT INFLUENT CONCENTRATIONS (C0)





1,3-Butadiene 0.000000 g/s 0.000000 g/m3




Methanol 1.0000 g/m3





Ethylene glycol 0.000000 g/s 0.000000 g/m3




Benzene 1.0000 g/m3





Methyl isobutyl ketone 0.000000 g/s 0.000000 g/m3




Carbon disulfide 1.0000 g/m3





Toluene 0.000000 g/s 0.000000 g/m3




Methyl ethyl ketone 1.0000 g/m3





Phenol 0.000000 g/s 0.000000 g/m3




Naphthalene 1.0000 g/m3





n-Hexane 0.000000 g/s 0.000000 g/m3




Cumene 1.0000 g/m3





Cresols (total) 0.000000 g/s 0.000000 g/m3




Ethylbenzene 1.0000 g/m3





Xylenes 0.000000 g/s 0.000000 g/m3




Styrene 0.0000 g/m3





Methyl tert-butyl ether 0.000000 g/s 0.000000 g/m3




1,3-Butadiene 0.0000 g/m3





Biphenyl, 1,1- 0.000000 g/s 0.000000 g/m3




Ethylene glycol 0.0000 g/m3





Carbonyl sulfide 0.000000 g/s 0.000000 g/m3




Methyl isobutyl ketone 0.0000 g/m3





Dichloroethane, 1,2- 0.000000 g/s 0.000000 g/m3




Toluene 0.0000 g/m3





Diethanolamine 0.000000 g/s 0.000000 g/m3




Phenol 0.0000 g/m3





Trimethylpentane, 2,2,4- 0.000000 g/s 0.000000 g/m3




n-Hexane 0.0000 g/m3





Compound A #DIV/0! g/s #DIV/0! g/m3




Cresols (total) 0.0000 g/m3





Compound B #DIV/0! g/s #DIV/0! g/m3




Xylenes 0.0000 g/m3





Compound C #DIV/0! g/s #DIV/0! g/m3




Methyl tert-butyl ether 0.0000 g/m3





n-Butane (VOC Surrogate) 0.000000 g/s 0.000000 g/m3




Biphenyl, 1,1- 0.0000 g/m3















Carbonyl sulfide 0.0000 g/m3















Dichloroethane, 1,2- 0.0000 g/m3















Diethanolamine 0.0000 g/m3















Trimethylpentane, 2,2,4- 0.0000 g/m3















Compound A 0.0000 g/m3















Compound B 0.0000 g/m3















Compound C 0.0000 g/m3















n-Butane (VOC Surrogate) 0.0000 g/m3


























































































































Windspeed (U10) 4.413 m/s





















































INTERMEDIATE OUTPUTS ScL ScG kl,q kg,q Keq KOL












Methanol 5.445E+02 1.006E+00 8.113E-06 1.127E-02 2.025E-04 1.781E-06












Benzene 9.112E+02 1.714E+00 6.498E-06 7.885E-03 2.483E-01 6.477E-06












Carbon disulfide 8.930E+02 1.450E+00 6.554E-06 8.819E-03 1.345E+00 6.551E-06












Methyl ethyl ketone 9.112E+02 1.867E+00 6.498E-06 7.447E-03 2.488E-03 4.811E-06












Naphthalene 1.191E+03 2.556E+00 5.810E-06 6.032E-03 2.150E-02 5.561E-06












Cumene 1.258E+03 1.754E+00 5.680E-06 7.765E-03 6.499E-01 5.674E-06












Ethylbenzene 1.145E+03 2.011E+00 5.905E-06 7.084E-03 3.507E-01 5.891E-06












Styrene 1.116E+03 2.124E+00 5.968E-06 6.829E-03 1.224E-01 5.925E-06












1,3-Butadiene 8.269E+02 6.058E-01 6.772E-06 1.583E-02 3.276E+00 6.771E-06












Ethylene glycol 6.333E+02 9.883E-01 7.595E-06 1.140E-02 8.012E-08 9.135E-10












Methyl isobutyl ketone 1.145E+03 2.011E+00 5.905E-06 7.084E-03 6.144E-03 5.200E-06












Toluene 1.038E+03 1.734E+00 6.151E-06 7.825E-03 2.955E-01 6.134E-06












Phenol 9.813E+02 1.839E+00 6.298E-06 7.521E-03 1.767E-05 1.302E-07












n-Hexane 1.149E+03 7.542E-01 5.896E-06 1.367E-02 5.430E+00 5.895E-06












Cresols (total) 9.602E+02 2.173E+00 6.356E-06 6.725E-03 7.211E-05 4.506E-07












Xylenes 9.561E+02 2.113E+00 6.368E-06 6.855E-03 2.689E-01 6.346E-06












Methyl tert-butyl ether 8.505E+02 1.473E+00 6.691E-06 8.728E-03 2.471E-02 6.490E-06












Biphenyl, 1,1- 1.089E+03 3.733E+00 6.029E-06 4.680E-03 1.246E-02 5.465E-06












Carbonyl sulfide 6.869E+02 9.328E-01 7.333E-06 1.185E-02 2.190E+00 7.331E-06












Dichloroethane, 1,2- 9.020E+02 1.450E+00 6.526E-06 8.819E-03 6.231E-02 6.450E-06












Diethanolamine 9.112E+02 2.143E+00 6.498E-06 6.790E-03 1.723E-09 1.170E-11












Trimethylpentane, 2,2,4- 1.355E+03 2.058E+00 5.509E-06 6.976E-03 1.349E+02 5.509E-06












Compound A #DIV/0! #DIV/0! #DIV/0! #DIV/0! 0.000E+00 #DIV/0!












Compound B #DIV/0! #DIV/0! #DIV/0! #DIV/0! 0.000E+00 #DIV/0!












Compound C #DIV/0! #DIV/0! #DIV/0! #DIV/0! 0.000E+00 #DIV/0!












n-Butane (VOC Surrogate) 8.670E+02 1.520E+00 6.637E-06 8.544E-03 4.228E+01 6.637E-06











































































































Parameters for kl,q calculation















U* 0.1315058450747 m/s















F/D 5.31923040535244






















































QUALITY CONTROL CHECKS

















Pollutant Influent load, g/s Effluent load, g/s Air emission load, g/s % Load with effluent % Load air emitted












Methanol 0.02 0.019 0.001 97 3












Benzene 0.02 0.001 0.019 7 93












Carbon disulfide 0.02 0.000 0.020 1 99












Methyl ethyl ketone 0.02 0.017 0.003 85 15












Naphthalene 0.02 0.009 0.011 47 53












Cumene 0.02 0.001 0.019 3 97












Ethylbenzene 0.02 0.001 0.019 5 95












Styrene 0 0.000 0.000 #DIV/0! #DIV/0!












1,3-Butadiene 0 0.000 0.000 #DIV/0! #DIV/0!












Ethylene glycol 0 0.000 0.000 #DIV/0! #DIV/0!












Methyl isobutyl ketone 0 0.000 0.000 #DIV/0! #DIV/0!












Toluene 0 0.000 0.000 #DIV/0! #DIV/0!












Phenol 0 0.000 0.000 #DIV/0! #DIV/0!












n-Hexane 0 0.000 0.000 #DIV/0! #DIV/0!












Cresols (total) 0 0.000 0.000 #DIV/0! #DIV/0!












Xylenes 0 0.000 0.000 #DIV/0! #DIV/0!












Methyl tert-butyl ether 0 0.000 0.000 #DIV/0! #DIV/0!












Biphenyl, 1,1- 0 0.000 0.000 #DIV/0! #DIV/0!












Carbonyl sulfide 0 0.000 0.000 #DIV/0! #DIV/0!












Dichloroethane, 1,2- 0 0.000 0.000 #DIV/0! #DIV/0!












Diethanolamine 0 0.000 0.000 #DIV/0! #DIV/0!












Trimethylpentane, 2,2,4- 0 0.000 0.000 #DIV/0! #DIV/0!












Compound A 0 #DIV/0! #DIV/0! #DIV/0! #DIV/0!












Compound B 0 #DIV/0! #DIV/0! #DIV/0! #DIV/0!












Compound C 0 #DIV/0! #DIV/0! #DIV/0! #DIV/0!












n-Butane (VOC Surrogate) 0 0.000 0.000 #DIV/0! #DIV/0!

Sheet 7: EQ Tanks
This sheet is used for uncovered equalization tanks only. Directions: 1) fill-in the input data (yellow boxes); review default variables and constant (yellow boxes) and change if necessary; 2) record air emissions (green boxes); and 3) record effluent concentrations (light blue boxes) for downstream process unit emission calculations.




















CRITICAL INPUTS VALUE UNITS
DEFAULT VARIABLES / CONSTANTS VALUE UNITS DEFAULT VALUE
AIR EMISSIONS VALUE UNITS EFFLUENT WATER CONCENTRATION UNITS











Surface area (A) 50000 m2
Viscosity of water (mL) 0.00893 g/cm-s 0.00893
Methanol 0.081088 g/s 0.082814 g/m3











Temperature (T) 19 deg. C
Density of water (ρL) 1 g/cm3 1
Benzene 0.084891 g/s 0.039801 g/m3











Total pressure (Po) 1 atm
Universal gas constant (R ) 8.21E-05 atm-m3/gmol-K 8.21E-05
Carbon disulfide 0.084931 g/s 0.039354 g/m3











Wastewater flow rate (Q) 0.08841 m3/s
Viscosity of air (ma) 0.000181 g/cm-s 0.000181
Methyl ethyl ketone 0.084185 g/s 0.047783 g/m3











Wastewater depth (D) 5 m
Density of air (ρa) 0.0012 g/cm3 0.0012
Naphthalene 0.084306 g/s 0.046426 g/m3











Total power to aerators (Ptot) 100 hp
Quiescent surface area (AQ) [default=A-AT] 0 m2 0
Cumene 0.084310 g/s 0.046379 g/m3











Number of aerators (Naer) 1 number
Oxygen transfer correction factor (Ot) 0.83 dimensionless 0.83
Ethylbenzene 0.084487 g/s 0.044378 g/m3











Windspeed (U10) 4.47 m/s
Oxygen transfer rating to surface area (J) 3 lb O2/hp-hr 3
Styrene 0.084523 g/s 0.043969 g/m3











Turbulent surface area (AT) 50000 m2
Impeller diameter (d) 61 cm 61
1,3-Butadiene 0.085058 g/s 0.037916 g/m3















Impeller diameter (d*) 2 ft 2
Ethylene glycol 0.000000 g/s 0.000000 g/m3















Rotational speed of impeller (w) 126 rad/s 126
Methyl isobutyl ketone 0.000000 g/s 0.000000 g/m3











CONSTITUENT INFLUENT CONCENTRATIONS (C0)
Diffusivity of ether in water (Dether) 8.50E-06 cm2/sec 8.50E-06
Toluene 0.000000 g/s 0.000000 g/m3











Methanol 1.0000 g/m3





Phenol 0.000000 g/s 0.000000 g/m3











Benzene 1.0000 g/m3





n-Hexane 0.000000 g/s 0.000000 g/m3











Carbon disulfide 1.0000 g/m3





Cresols (total) 0.000000 g/s 0.000000 g/m3











Methyl ethyl ketone 1.0000 g/m3





Xylenes 0.000000 g/s 0.000000 g/m3











Naphthalene 1.0000 g/m3





Methyl tert-butyl ether 0.000000 g/s 0.000000 g/m3











Cumene 1.0000 g/m3





Biphenyl, 1,1- 0.000000 g/s 0.000000 g/m3











Ethylbenzene 1.0000 g/m3





Carbonyl sulfide 0.000000 g/s 0.000000 g/m3











Styrene 1.0000 g/m3





Dichloroethane, 1,2- 0.000000 g/s 0.000000 g/m3











1,3-Butadiene 1.0000 g/m3





Diethanolamine 0.000000 g/s 0.000000 g/m3











Ethylene glycol 0.0000 g/m3





Trimethylpentane, 2,2,4- 0.000000 g/s 0.000000 g/m3











Methyl isobutyl ketone 0.0000 g/m3





Compound A #DIV/0! g/s #DIV/0! g/m3











Toluene 0.0000 g/m3





Compound B #DIV/0! g/s #DIV/0! g/m3











Phenol 0.0000 g/m3





Compound C #DIV/0! g/s #DIV/0! g/m3











n-Hexane 0.0000 g/m3





n-Butane (VOC Surrogate) 0.000000 g/s 0.000000 g/m3











Cresols (total) 0.0000 g/m3






















Xylenes 0.0000 g/m3






















Methyl tert-butyl ether 0.0000 g/m3






















Biphenyl, 1,1- 0.0000 g/m3






















Carbonyl sulfide 0.0000 g/m3





















495.95
Dichloroethane, 1,2- 0.0000 g/m3





















282.625
Diethanolamine 0.0000 g/m3





















534.95
Trimethylpentane, 2,2,4- 0.0000 g/m3





















267.475
Compound A 0.0000 g/m3





















133.7375
Compound B 0.0000 g/m3






















Compound C 0.0000 g/m3






















n-Butane (VOC Surrogate) 0.0000 g/m3






















































































Windspeed (U10) 4.47 m/s








































































INTERMEDIATE OUTPUTS ScL ScG kl,q kg,q kl,t kg,t Keq KT KQ KOL














Methanol 5.445E+02 1.006E+00 8.025E-06 8.403E-03 5.529E-05 1.599E-01 1.897E-04 1.958E-05 1.330E-06 1.958E-05














Benzene 9.112E+02 1.714E+00 5.694E-06 5.879E-03 4.274E-05 9.378E-02 2.326E-01 4.266E-05 5.670E-06 4.266E-05














Carbon disulfide 8.930E+02 1.450E+00 5.771E-06 6.575E-03 4.318E-05 1.108E-01 1.260E+00 4.316E-05 5.767E-06 4.316E-05














Methyl ethyl ketone 9.112E+02 1.867E+00 5.694E-06 5.552E-03 4.274E-05 8.611E-02 2.331E-03 3.524E-05 3.954E-06 3.524E-05














Naphthalene 1.191E+03 2.556E+00 4.764E-06 4.497E-03 3.739E-05 6.287E-02 2.014E-02 3.632E-05 4.526E-06 3.632E-05














Cumene 1.258E+03 1.754E+00 4.593E-06 5.789E-03 3.638E-05 9.165E-02 6.087E-01 3.636E-05 4.587E-06 3.636E-05














Ethylbenzene 1.145E+03 2.011E+00 4.890E-06 5.282E-03 3.813E-05 7.993E-02 3.285E-01 3.808E-05 4.876E-06 3.808E-05














Styrene 1.116E+03 2.124E+00 4.973E-06 5.091E-03 3.862E-05 7.566E-02 1.147E-01 3.845E-05 4.931E-06 3.845E-05














1,3-Butadiene 8.269E+02 6.058E-01 6.075E-06 1.180E-02 4.487E-05 2.654E-01 3.069E+00 4.487E-05 6.073E-06 4.487E-05














Ethylene glycol 6.333E+02 9.883E-01 7.256E-06 8.501E-03 5.127E-05 1.626E-01 7.505E-08 1.220E-08 6.379E-10 1.220E-08














Methyl isobutyl ketone 1.145E+03 2.011E+00 4.890E-06 5.282E-03 3.813E-05 7.993E-02 5.755E-03 3.521E-05 4.212E-06 3.521E-05














Toluene 1.038E+03 1.734E+00 5.219E-06 5.834E-03 4.004E-05 9.271E-02 2.768E-01 3.998E-05 5.202E-06 3.998E-05














Phenol 9.813E+02 1.839E+00 5.419E-06 5.607E-03 4.119E-05 8.738E-02 1.655E-05 1.397E-06 9.124E-08 1.397E-06














n-Hexane 1.149E+03 7.542E-01 4.877E-06 1.019E-02 3.806E-05 2.131E-01 5.086E+00 3.806E-05 4.877E-06 3.806E-05














Cresols (total) 9.602E+02 2.173E+00 5.498E-06 5.014E-03 4.164E-05 7.396E-02 6.754E-05 4.460E-06 3.190E-07 4.460E-06














Xylenes 9.561E+02 2.113E+00 5.514E-06 5.110E-03 4.173E-05 7.609E-02 2.519E-01 4.164E-05 5.490E-06 4.164E-05














Methyl tert-butyl ether 8.505E+02 1.473E+00 5.961E-06 6.507E-03 4.424E-05 1.091E-01 2.314E-02 4.348E-05 5.734E-06 4.348E-05














Biphenyl, 1,1- 1.089E+03 3.733E+00 5.056E-06 3.489E-03 3.910E-05 4.305E-02 1.167E-02 3.628E-05 4.497E-06 3.628E-05














Carbonyl sulfide 6.869E+02 9.328E-01 6.874E-06 8.837E-03 4.923E-05 1.723E-01 2.051E+00 4.922E-05 6.871E-06 4.922E-05














Dichloroethane, 1,2- 9.020E+02 1.450E+00 5.732E-06 6.575E-03 4.296E-05 1.108E-01 5.837E-02 4.268E-05 5.648E-06 4.268E-05














Diethanolamine 9.112E+02 2.143E+00 5.694E-06 5.062E-03 4.274E-05 7.502E-02 1.613E-09 1.210E-10 8.168E-12 1.210E-10














Trimethylpentane, 2,2,4- 1.355E+03 2.058E+00 4.370E-06 5.201E-03 3.505E-05 7.811E-02 1.263E+02 3.505E-05 4.370E-06 3.505E-05














Compound A #DIV/0! #DIV/0! 0.000E+00 #DIV/0! 0.000E+00 0.000E+00 0.000E+00 #DIV/0! #DIV/0! #DIV/0!














Compound B #DIV/0! #DIV/0! 0.000E+00 #DIV/0! 0.000E+00 0.000E+00 0.000E+00 #DIV/0! #DIV/0! #DIV/0!














Compound C #DIV/0! #DIV/0! 0.000E+00 #DIV/0! 0.000E+00 0.000E+00 0.000E+00 #DIV/0! #DIV/0! #DIV/0!














n-Butane (VOC Surrogate) 8.670E+02 1.520E+00 5.886E-06 6.370E-03 4.382E-05 1.057E-01 3.961E+01 4.382E-05 5.885E-06 4.382E-05
















































































































































Power number (P) 3.751E-04























Reynolds number (Re) 3.108E+06























Froude number (Fr) 9.874E+02























Turbulent surface area (Vav), ft2 5.379E+05























F/D 5.046E+01























Effective Diameter (de) 2.524E+02























U* 1.335E-01































































































































QUALITY CONTROL CHECKS



















Pollutant Influent load, g/s Effluent load, g/s Air emission load, g/s % Load with effluent % Load air emitted



















Methanol 0.08841 0.007 0.081 8 92



















Benzene 0.08841 0.004 0.085 4 96



















Carbon disulfide 0.08841 0.003 0.085 4 96



















Methyl ethyl ketone 0.08841 0.004 0.084 5 95



















Naphthalene 0.08841 0.004 0.084 5 95



















Cumene 0.08841 0.004 0.084 5 95



















Ethylbenzene 0.08841 0.004 0.084 4 96



















Styrene 0.08841 0.004 0.085 4 96



















1,3-Butadiene 0.08841 0.003 0.085 4 96



















Ethylene glycol 0 0.000 0.000 #DIV/0! #DIV/0!



















Methyl isobutyl ketone 0 0.000 0.000 #DIV/0! #DIV/0!



















Toluene 0 0.000 0.000 #DIV/0! #DIV/0!



















Phenol 0 0.000 0.000 #DIV/0! #DIV/0!



















n-Hexane 0 0.000 0.000 #DIV/0! #DIV/0!



















Cresols (total) 0 0.000 0.000 #DIV/0! #DIV/0!



















Xylenes 0 0.000 0.000 #DIV/0! #DIV/0!



















Methyl tert-butyl ether 0 0.000 0.000 #DIV/0! #DIV/0!



















Biphenyl, 1,1- 0 0.000 0.000 #DIV/0! #DIV/0!



















Carbonyl sulfide 0 0.000 0.000 #DIV/0! #DIV/0!



















Dichloroethane, 1,2- 0 0.000 0.000 #DIV/0! #DIV/0!



















Diethanolamine 0 0.000 0.000 #DIV/0! #DIV/0!



















Trimethylpentane, 2,2,4- 0 0.000 0.000 #DIV/0! #DIV/0!



















Compound A 0 #DIV/0! #DIV/0! #DIV/0! #DIV/0!



















Compound B 0 #DIV/0! #DIV/0! #DIV/0! #DIV/0!



















Compound C 0 #DIV/0! #DIV/0! #DIV/0! #DIV/0!



















n-Butane (VOC Surrogate) 0 0.000 0.000 #DIV/0! #DIV/0!







Sheet 8: Bio. Diff. Aer. Act. Sldg.
This sheet is used for uncovered biological treatment units with diffused aeration only. Directions: 1) fill-in the input data (yellow boxes); review default variables and constant (yellow boxes) and change if necessary; 2) record air emissions (green boxes); and 3) record effluent concentrations (light blue boxes) for downstream process unit emission calculations.






















CRITICAL INPUTS VALUE UNITS
DEFAULT VARIABLES / CONSTANTS VALUE UNITS DEFAULT VALUE
AIR EMISSIONS VALUE UNITS EFFLUENT WATER CONCENTRATION UNITS













Windspeed (U10) 4.47 m/s
Viscosity of water (mL) 0.00893 g/cm-s 0.00893
Methanol 0.000827 g/s 0.412703 g/m3













Surface area (A) 1225 m2
Density of water (ρL) 1 g/cm3 1
Benzene 0.088469 g/s 0.083305 g/m3













Temperature (T) 25 deg. C
Universal gas constant (R ) 8.21E-05 atm-m3/gmol-K 8.21E-05
Carbon disulfide 0.436140 g/s 0.076655 g/m3













Total pressure (Po) 1 atm
Viscosity of air (ma) 0.000181 g/cm-s 0.000181
Methyl ethyl ketone 0.005898 g/s 0.419445 g/m3













Wastewater flow rate (Q) 1 m3/s
Density of air (ρa) 0.0012 g/cm3 0.0012
Naphthalene 0.011671 g/s 0.121528 g/m3













Wastewater depth (D) 7 m
Quiescent surface area (AQ) [default=A-AT] 725 m2 725
Cumene 0.113505 g/s 0.041197 g/m3













Biological treatment unit suspended solids (CMLSS) 3000 g/m3
Oxygen transfer correction factor (Ot) 0.83 dimensionless 0.83
Ethylbenzene 0.086630 g/s 0.058007 g/m3













Turbulent surface area (AT) 500 m2
Oxygen transfer rating to surface area (J) 3 lb O2/hp-hr 3
Styrene 0.000000 g/s 0.000000 g/m3













Diffused air volumetric flow rate (Qa) 3.51 m3/s
Weight fraction of carbon in biomass (foc) 0.33 dimensionless 0.33
1,3-Butadiene 0.000000 g/s 0.000000 g/m3













Wasted sludge volumetric flow rate (Qw) 0.0016 m3/s
Diffusivity of ether in water (Dether) 8.50E-06 cm2/sec 8.50E-06
Ethylene glycol 0.000000 g/s 0.000000 g/m3













Biological treatment unit volatile suspended solids (CMLVSS) 1500 g/m3
Biomass volatile suspend solids yield from influent BOD (Y) 0.67 g VSS/g BOD 6.70E-01
Methyl isobutyl ketone 0.000000 g/s 0.000000 g/m3













Influent 5-day biochemcial oxygen demand concentration (CBOD5,i) 150 g/m3





Toluene 0.000000 g/s 0.000000 g/m3













Wasted sludge volatile suspended solids (CWAS,VSS) 15000 g/m3





Phenol 0.000000 g/s 0.000000 g/m3













Blower gauge pressure (Pg) 9 lb/in2





n-Hexane 0.000000 g/s 0.000000 g/m3






















Cresols (total) 0.000000 g/s 0.000000 g/m3






















Xylenes 0.000000 g/s 0.000000 g/m3













CONSTITUENT INFLUENT CONCENTRATIONS (C0)





Methyl tert-butyl ether 0.000000 g/s 0.000000 g/m3













Methanol 1.0000 g/m3





Biphenyl, 1,1- 0.000000 g/s 0.000000 g/m3













Benzene 1.0000 g/m3





Carbonyl sulfide 0.000000 g/s 0.000000 g/m3













Carbon disulfide 1.0000 g/m3





Dichloroethane, 1,2- 0.000000 g/s 0.000000 g/m3













Methyl ethyl ketone 1.0000 g/m3





Diethanolamine 0.000000 g/s 0.000000 g/m3













Naphthalene 1.0000 g/m3





Trimethylpentane, 2,2,4- 0.000000 g/s 0.000000 g/m3













Cumene 1.0000 g/m3





Compound A #DIV/0! g/s #DIV/0! g/m3













Ethylbenzene 1.0000 g/m3





Compound B #DIV/0! g/s #DIV/0! g/m3













Styrene 0.0000 g/m3





Compound C #DIV/0! g/s #DIV/0! g/m3













1,3-Butadiene 0.0000 g/m3





n-Butane (VOC Surrogate) 0.000000 g/s 0.000000 g/m3













Ethylene glycol 0.0000 g/m3
























Methyl isobutyl ketone 0.0000 g/m3
























Toluene 0.0000 g/m3
























Phenol 0.0000 g/m3
























n-Hexane 0.0000 g/m3
























Cresols (total) 0.0000 g/m3
























Xylenes 0.0000 g/m3
























Methyl tert-butyl ether 0.0000 g/m3
























Biphenyl, 1,1- 0.0000 g/m3
























Carbonyl sulfide 0.0000 g/m3
























Dichloroethane, 1,2- 0.0000 g/m3
























Diethanolamine 0.0000 g/m3
























Trimethylpentane, 2,2,4- 0.0000 g/m3
























Compound A 0.0000 g/m3
























Compound B 0.0000 g/m3








Windspeed (U10) 4.47 m/s












Compound C 0.0000 g/m3
























n-Butane (VOC Surrogate) 0.0000 g/m3


































INTERMEDIATE OUTPUTS ScL ScG kl,q kl,t kg,q kg,t KT KQ Keq KOL a b c kabs f












Methanol 5.445E+02 1.006E+00 8.349E-06 7.74106664245486E-05 1.030E-02 0.000232231999274 4.314E-08 1.558E-06 1.859E-04 9.397E-07 1.000E+00 2.177E+02 -9.000E+01 3.080E-08












Benzene 9.112E+02 1.714E+00 6.681E-06 5.98400461941365E-05 7.209E-03 0.000179520138582 2.430E-05 6.654E-06 2.279E-01 1.386E-05 2.061E+00 1.627E+02 -1.357E+01 2.131E-05












Carbon disulfide 8.930E+02 1.450E+00 6.739E-06 6.04475749291288E-05 8.063E-03 0.000181342724787 4.760E-05 6.734E-06 1.235E+00 2.341E-05 6.688E+00 2.228E+02 -1.712E+01 1.579E-05












Methyl ethyl ketone 9.112E+02 1.867E+00 6.681E-06 5.98400461941365E-05 6.808E-03 0.000179520138582 4.072E-07 4.673E-06 2.284E-03 2.932E-06 1.012E+00 2.342E+01 -1.000E+01 3.010E-07












Naphthalene 1.191E+03 2.556E+00 5.970E-06 5.23491354857889E-05 5.515E-03 0.000157047406457 2.926E-06 5.659E-06 1.973E-02 4.544E-06 1.103E+00 3.493E+02 -4.247E+01 3.618E-04












Cumene 1.258E+03 1.754E+00 5.835E-06 5.0934031977814E-05 7.099E-03 0.000152802095933 3.267E-05 5.827E-06 5.965E-01 1.679E-05 3.768E+00 2.619E+02 -1.080E+01 6.005E-04












Ethylbenzene 1.145E+03 2.011E+00 6.068E-06 5.338585267235E-05 6.477E-03 0.000160157558017 2.623E-05 6.051E-06 3.219E-01 1.429E-05 2.497E+00 5.568E+01 -3.238E+00 2.180E-04












Styrene 1.116E+03 2.124E+00 6.133E-06 5.40659546466176E-05 6.243E-03 0.00016219786394 1.363E-05 6.080E-06 1.123E-01 9.161E-06 1.528E+00 6.542E+02 0.000E+00 1.376E-04












1,3-Butadiene 8.269E+02 6.058E-01 6.964E-06 6.28189625829466E-05 1.447E-02 0.000188456887749 5.655E-05 6.963E-06 3.007E+00 2.720E-05 1.482E+01 4.360E+02 0.000E+00 1.544E-05












Ethylene glycol 6.333E+02 9.883E-01 7.814E-06 7.17775183040332E-05 1.043E-02 0.000215332554912 1.583E-11 7.665E-10 7.354E-08 4.601E-10 9.984E-01 4.148E+02 0.000E+00 1.441E-09












Methyl isobutyl ketone 1.145E+03 2.011E+00 6.068E-06 5.338585267235E-05 6.477E-03 0.000160157558017 8.881E-07 5.204E-06 5.639E-03 3.442E-06 1.029E+00 6.973E+00 0.000E+00 2.446E-06












Toluene 1.038E+03 1.734E+00 6.322E-06 5.60567748870631E-05 7.154E-03 0.000168170324661 2.515E-05 6.301E-06 2.713E-01 1.399E-05 2.261E+00 5.943E+02 0.000E+00 8.882E-05












Phenol 9.813E+02 1.839E+00 6.474E-06 5.76633113554841E-05 6.876E-03 0.000172989934066 2.806E-09 1.096E-07 1.622E-05 6.603E-08 9.987E-01 7.006E+02 0.000E+00 4.770E-06












n-Hexane 1.149E+03 7.542E-01 6.058E-06 5.32830886643166E-05 1.250E-02 0.000159849265993 4.994E-05 6.058E-06 4.984E+00 2.397E-05 2.392E+01 3.585E+02 0.000E+00 1.579E-03












Cresols (total) 9.602E+02 2.173E+00 6.534E-06 5.82935301965472E-05 6.149E-03 0.00017488059059 1.157E-08 3.831E-07 6.618E-05 2.314E-07 9.990E-01 1.657E+02 0.000E+00 1.579E-07












Xylenes 9.561E+02 2.113E+00 6.546E-06 5.84187581178769E-05 6.267E-03 0.000175256274354 2.485E-05 6.518E-06 2.468E-01 1.400E-05 2.153E+00 3.403E+02 0.000E+00 2.336E-04












Methyl tert-butyl ether 8.505E+02 1.473E+00 6.880E-06 6.19403324220437E-05 7.979E-03 0.000185820997266 3.946E-06 6.628E-06 2.268E-02 5.533E-06 1.109E+00 1.528E+02 0.000E+00 1.259E-05












Biphenyl, 1,1- 1.089E+03 3.733E+00 6.197E-06 5.47376071649681E-05 4.279E-03 0.000164212821495 1.816E-06 5.500E-06 1.144E-02 3.996E-06 1.078E+00 1.504E+02 0.000E+00 9.089E-04












Carbonyl sulfide 6.869E+02 9.328E-01 7.543E-06 6.89208394410314E-05 1.084E-02 0.000206762518323 5.912E-05 7.540E-06 2.010E+00 2.859E-05 1.025E+01 2.849E+02 0.000E+00 9.987E-07












Dichloroethane, 1,2- 9.020E+02 1.450E+00 6.710E-06 6.01445776580442E-05 8.063E-03 0.000180433732974 8.808E-06 6.614E-06 5.719E-02 7.509E-06 1.270E+00 1.773E+01 0.000E+00 4.770E-06












Diethanolamine 9.112E+02 2.143E+00 6.681E-06 5.98400461941365E-05 6.208E-03 0.000179520138582 2.838E-13 9.815E-12 1.581E-09 5.924E-12 9.984E-01 1.265E+02 0.000E+00 5.868E-09












Trimethylpentane, 2,2,4- 1.355E+03 2.058E+00 5.659E-06 4.90706250058172E-05 6.378E-03 0.000147211875017 4.894E-05 5.658E-06 1.238E+02 2.332E-05 5.711E+02 6.060E+03 0.000E+00 1.068E-01












Compound A #DIV/0! #DIV/0! #DIV/0! 0 #DIV/0! 0 #DIV/0! #DIV/0! 0.000E+00 #DIV/0! #DIV/0! #DIV/0! 0.000E+00 1.579E-07












Compound B #DIV/0! #DIV/0! #DIV/0! 0 #DIV/0! 0 #DIV/0! #DIV/0! 0.000E+00 #DIV/0! #DIV/0! #DIV/0! 0.000E+00 1.579E-07












Compound C #DIV/0! #DIV/0! #DIV/0! 0 #DIV/0! 0 #DIV/0! #DIV/0! 0.000E+00 #DIV/0! #DIV/0! #DIV/0! 0.000E+00 1.579E-07












n-Butane (VOC Surrogate) 8.670E+02 1.520E+00 6.824E-06 6.13475883328515E-05 7.811E-03 0.000184042764999 6.083E-05 6.824E-06 3.881E+01 2.887E-05 1.790E+02 1.974E+03 0.000E+00 1.226E-04
























































































































































Average volumetric air flow rate, m3/s 4.585E+00

























Fraction of area agitated (Vav), ft2 3.163E+03

























F/D 5.642E+00

























Effective Diameter (de) 3.950E+01

























U* 1.335E-01

























NH3 KLa, s-1 2.27325135988852E-05

























a, m-1 0.142857142857143

























NH3 KL, m/s 0.000159127595192





















































QUALITY CONTROL CHECKS



















Pollutant Influent load, g/s Effluent load, g/s Air emission load, g/s Absorbed load, g/s Biodegradation rate, g/s % Load with effluent % Load air emitted % Biodegraded % Load absorbed Mass balance Check
















Methanol 1 0.412 0.001 0.000 0.587 41 0 59 0.00 100
















Benzene 1 0.083 0.088 0.000 0.828 8 9 83 0.00 100
















Carbon disulfide 1 0.077 0.436 0.000 0.487 8 44 49 0.00 100
















Methyl ethyl ketone 1 0.419 0.006 0.000 0.575 42 1 58 0.00 100
















Naphthalene 1 0.121 0.012 0.001 0.866 12 1 87 0.11 100
















Cumene 1 0.041 0.114 0.001 0.845 4 11 84 0.06 100
















Ethylbenzene 1 0.058 0.087 0.000 0.855 6 9 86 0.03 100
















Styrene 0 0.000 0.000 0.000 0.000 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
















1,3-Butadiene 0 0.000 0.000 0.000 0.000 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
















Ethylene glycol 0 0.000 0.000 0.000 0.000 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
















Methyl isobutyl ketone 0 0.000 0.000 0.000 0.000 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
















Toluene 0 0.000 0.000 0.000 0.000 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
















Phenol 0 0.000 0.000 0.000 0.000 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
















n-Hexane 0 0.000 0.000 0.000 0.000 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
















Cresols (total) 0 0.000 0.000 0.000 0.000 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
















Xylenes 0 0.000 0.000 0.000 0.000 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
















Methyl tert-butyl ether 0 0.000 0.000 0.000 0.000 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
















Biphenyl, 1,1- 0 0.000 0.000 0.000 0.000 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
















Carbonyl sulfide 0 0.000 0.000 0.000 0.000 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
















Dichloroethane, 1,2- 0 0.000 0.000 0.000 0.000 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
















Diethanolamine 0 0.000 0.000 0.000 0.000 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
















Trimethylpentane, 2,2,4- 0 0.000 0.000 0.000 0.000 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
















Compound A 0 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
















Compound B 0 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
















Compound C 0 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
















n-Butane (VOC Surrogate) 0 0.000 0.000 0.000 0.000 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!




Sheet 9: Bio. Mech. Aer. Act. Sldg.
This sheet is used for biological treatment units with mechanical aeration only. Directions: 1) fill-in the input data (yellow boxes); review default variables and constant (yellow boxes) and change if necessary; 2) record air emissions (green boxes); and 3) record effluent concentrations (light blue boxes) for downstream process unit emission calculations.
























CRITICAL INPUTS VALUE UNITS
DEFAULT VARIABLES / CONSTANTS VALUE UNITS DEFAULT VALUE
AIR EMISSIONS VALUE UNITS EFFLUENT WATER CONCENTRATION UNITS















Surface area (A) 1225 m2
Viscosity of water (mL) 0.00893 g/cm-s 0.00893
Methanol 0.005677 g/s 0.428136 g/m3















Temperature (T) 25 deg. C
Density of water (ρL) 1 g/cm3 1
Benzene 0.291972 g/s 0.065026 g/m3















Total pressure (Po) 1 atm
Universal gas constant (R ) 8.21E-05 atm-m3/gmol-K 8.21E-05
Carbon disulfide 0.480083 g/s 0.071391 g/m3















Wastewater flow rate (Q) 1 m3/s
Viscosity of air (ma) 0.000181 g/cm-s 0.000181
Methyl ethyl ketone 0.046701 g/s 0.419573 g/m3















Wastewater depth (D) 7 m
Density of air (ρa) 0.0012 g/cm3 0.0012
Naphthalene 0.077779 g/s 0.107604 g/m3















Total power to aerators (Ptot) 300 hp
Quiescent area (AQ) [default=A-AT] 725 m2 725
Cumene 0.188693 g/s 0.036356 g/m3















Number of aerators (Naer) 5 number
Oxygen transfer correction factor (Ot) 0.83 dimensionless 0.83
Ethylbenzene 0.222164 g/s 0.048580 g/m3















Biological treatment unit volatile suspended solids (CMLVSS) 3000 g/m3
Oxygen transfer rating to surface area (J) 3 lb O2/hp-hr 3
Styrene 0.603553 g/s 0.209560 g/m3















Windspeed (U10) 4.47 m/s
Impeller diameter (d) 61 cm 61
1,3-Butadiene 0.562249 g/s 0.074630 g/m3















Wasted sludge volumetric flow rate (Qw) 0.1 m3/s
Impeller diameter (d*) 2 ft 2
Ethylene glycol 0.000004 g/s 0.750792 g/m3















Turbulent area (AT) 500 m2
Rotational speed of impeller (w) 126 rad/s 126
Methyl isobutyl ketone 0.064350 g/s 0.252939 g/m3















Influent 5-day biochemcial oxygen demand concentration (CBOD5,i) 250 g/m3
Diffusivity of ether in water (Dether) 8.50E-06 cm2/sec 8.50E-06
Toluene 0.201462 g/s 0.043976 g/m3















Wasted sludge volatile suspended solids (CWAS,VSS) 15000 g/m3
Weight fraction of carbon in biomass (foc) 0.33 dimensionless 0.33
Phenol 0.000009 g/s 0.010676 g/m3



















Biomass volatile suspend solids yield from influent BOD (Y) 0.67 g VSS/g BOD 0.67
n-Hexane 0.320674 g/s 0.049541 g/m3
























Cresols (total) 0.000026 g/s 0.008220 g/m3















CONSTITUENT INFLUENT CONCENTRATIONS (C0)





Xylenes 0.237317 g/s 0.054159 g/m3















Methanol 1.0000 g/m3





Methyl tert-butyl ether 0.150546 g/s 0.141992 g/m3















Benzene 1.0000 g/m3





Biphenyl, 1,1- 0.029478 g/s 0.079491 g/m3















Carbon disulfide 1.0000 g/m3





Carbonyl sulfide 0.524557 g/s 0.065418 g/m3















Methyl ethyl ketone 1.0000 g/m3





Dichloroethane, 1,2- 0.224535 g/s 0.102157 g/m3















Naphthalene 1.0000 g/m3





Diethanolamine 0.000000 g/s 0.595409 g/m3















Cumene 1.0000 g/m3





Trimethylpentane, 2,2,4- 0.034111 g/s 0.005630 g/m3















Ethylbenzene 1.0000 g/m3





Compound A #DIV/0! g/s #DIV/0! g/m3















Styrene 1.0000 g/m3





Compound B #DIV/0! g/s #DIV/0! g/m3















1,3-Butadiene 1.0000 g/m3





Compound C #DIV/0! g/s #DIV/0! g/m3















Ethylene glycol 1.0000 g/m3





n-Butane (VOC Surrogate) 0.395984 g/s 0.052413 g/m3















Methyl isobutyl ketone 1.0000 g/m3


























Toluene 1.0000 g/m3


























Phenol 1.0000 g/m3


























n-Hexane 1.0000 g/m3


























Cresols (total) 1.0000 g/m3


























Xylenes 1.0000 g/m3


























Methyl tert-butyl ether 1.0000 g/m3


























Biphenyl, 1,1- 1.0000 g/m3


























Carbonyl sulfide 1.0000 g/m3


























Dichloroethane, 1,2- 1.0000 g/m3


























Diethanolamine 1.0000 g/m3


























Trimethylpentane, 2,2,4- 1.0000 g/m3


























Compound A 1.0000 g/m3


























Compound B 1.0000 g/m3


























Compound C 1.0000 g/m3








Windspeed (U10) 4.47 m/s














n-Butane (VOC Surrogate) 1.0000 g/m3


































































INTERMEDIATE OUTPUTS ScL ScG kl,q kg,q kl,t kg,t Keq KT KQ KOL a b c kabs a1 b1 c1












Methanol 5.445E+02 1.006E+00 8.349E-06 1.030E-02 1.912E-02 1.307E-01 1.859E-04 2.426E-05 1.558E-06 1.082E-05 9.133E-01 2.098E+02 -9.000E+01 3.080E-08 1.013E+00 2.098E+02 -9.000E+01












Benzene 9.112E+02 1.714E+00 6.681E-06 7.209E-03 1.478E-02 1.001E-01 2.279E-01 8.971E-03 6.654E-06 3.665E-03 5.422E+00 2.084E+02 -1.357E+01 2.131E-05 5.492E+00 2.079E+02 -1.357E+01










Carbon disulfide 8.930E+02 1.450E+00 6.739E-06 8.063E-03 1.493E-02 1.088E-01 1.235E+00 1.344E-02 6.734E-06 5.490E-03 7.648E+00 2.393E+02 -1.712E+01 1.579E-05 7.726E+00 2.389E+02 -1.712E+01












Methyl ethyl ketone 9.112E+02 1.867E+00 6.681E-06 6.808E-03 1.478E-02 9.591E-02 2.284E-03 2.158E-04 4.673E-06 9.086E-05 1.012E+00 2.341E+01 -1.000E+01 3.010E-07 1.111E+00 2.341E+01 -1.000E+01












Naphthalene 1.191E+03 2.556E+00 5.970E-06 5.515E-03 1.293E-02 8.196E-02 1.973E-02 1.437E-03 5.659E-06 5.901E-04 2.166E+00 3.945E+02 -4.247E+01 3.618E-04 1.757E+00 3.729E+02 -4.247E+01












Cumene 1.258E+03 1.754E+00 5.835E-06 7.099E-03 1.258E-02 9.895E-02 5.965E-01 1.037E-02 5.827E-06 4.237E-03 6.991E+00 2.967E+02 -1.080E+01 6.005E-04 6.248E+00 2.876E+02 -1.080E+01












Ethylbenzene 1.145E+03 2.011E+00 6.068E-06 6.477E-03 1.319E-02 9.241E-02 3.219E-01 9.138E-03 6.051E-06 3.733E-03 5.800E+00 6.637E+01 -3.238E+00 2.180E-04 5.594E+00 6.538E+01 -3.238E+00












Styrene 1.116E+03 2.124E+00 6.133E-06 6.243E-03 1.336E-02 8.991E-02 1.123E-01 5.751E-03 6.080E-06 2.351E-03 3.986E+00 1.348E+03 -2.827E+02 1.376E-04 3.893E+00 1.294E+03 -2.827E+02












1,3-Butadiene 8.269E+02 6.058E-01 6.964E-06 1.447E-02 1.552E-02 1.684E-01 3.007E+00 1.506E-02 6.963E-06 6.150E-03 8.457E+00 2.948E+02 -2.205E+01 1.544E-05 8.535E+00 2.943E+02 -2.205E+01












Ethylene glycol 6.333E+02 9.883E-01 7.814E-06 1.043E-02 1.773E-02 1.318E-01 7.354E-08 9.693E-09 7.665E-10 4.410E-09 9.000E-01 3.853E+02 -2.898E+02 1.441E-09 1.000E+00 3.853E+02 -2.898E+02












Methyl isobutyl ketone 1.145E+03 2.011E+00 6.068E-06 6.477E-03 1.319E-02 9.241E-02 5.639E-03 5.013E-04 5.204E-06 2.077E-04 1.158E+00 6.186E+00 -1.639E+00 2.446E-06 1.255E+00 6.180E+00 -1.639E+00












Toluene 1.038E+03 1.734E+00 6.322E-06 7.154E-03 1.385E-02 9.952E-02 2.713E-01 9.153E-03 6.301E-06 3.740E-03 5.614E+00 6.960E+02 -3.062E+01 8.882E-05 5.590E+00 6.922E+02 -3.062E+01












Phenol 9.813E+02 1.839E+00 6.474E-06 6.876E-03 1.425E-02 9.662E-02 1.622E-05 1.567E-06 1.096E-07 7.044E-07 9.080E-01 6.989E+02 -7.462E+00 4.770E-06 1.001E+00 6.989E+02 -7.462E+00












n-Hexane 1.149E+03 7.542E-01 6.058E-06 1.250E-02 1.316E-02 1.509E-01 4.984E+00 1.294E-02 6.058E-06 5.284E-03 9.742E+00 2.098E+02 -1.042E+01 1.579E-03 7.624E+00 1.867E+02 -1.042E+01












Cresols (total) 9.602E+02 2.173E+00 6.534E-06 6.149E-03 1.440E-02 8.889E-02 6.618E-05 5.880E-06 3.831E-07 2.627E-06 9.035E-01 1.646E+02 -1.353E+00 1.579E-07 1.003E+00 1.646E+02 -1.353E+00












Xylenes 9.561E+02 2.113E+00 6.546E-06 6.267E-03 1.443E-02 9.016E-02 2.468E-01 8.754E-03 6.518E-06 3.577E-03 5.632E+00 4.182E+02 -2.267E+01 2.336E-04 5.404E+00 4.108E+02 -2.267E+01












Methyl tert-butyl ether 8.505E+02 1.473E+00 6.880E-06 7.979E-03 1.530E-02 1.080E-01 2.268E-02 2.111E-03 6.628E-06 8.655E-04 1.979E+00 1.732E+02 -2.464E+01 1.259E-05 2.061E+00 1.728E+02 -2.464E+01












Biphenyl, 1,1- 1.089E+03 3.733E+00 6.197E-06 4.279E-03 1.352E-02 6.782E-02 1.144E-02 7.337E-04 5.500E-06 3.027E-04 2.634E+00 1.705E+02 -1.357E+01 9.089E-04 1.458E+00 1.532E+02 -1.357E+01












Carbonyl sulfide 6.869E+02 9.328E-01 7.543E-06 1.084E-02 1.703E-02 1.357E-01 2.010E+00 1.603E-02 7.540E-06 6.546E-03 8.920E+00 2.611E+02 -1.712E+01 9.987E-07 9.019E+00 2.611E+02 -1.712E+01












Dichloroethane, 1,2- 9.020E+02 1.450E+00 6.710E-06 8.063E-03 1.486E-02 1.088E-01 5.719E-02 4.386E-03 6.614E-06 1.794E-03 3.105E+00 2.066E+01 -2.143E+00 4.770E-06 3.198E+00 2.064E+01 -2.143E+00












Diethanolamine 9.112E+02 2.143E+00 6.681E-06 6.208E-03 1.478E-02 8.953E-02 1.581E-09 1.415E-10 9.815E-12 6.358E-11 9.000E-01 1.186E+02 -7.091E+01 5.868E-09 1.000E+00 1.186E+02 -7.091E+01












Trimethylpentane, 2,2,4- 1.355E+03 2.058E+00 5.659E-06 6.378E-03 1.212E-02 9.135E-02 1.238E+02 1.211E-02 5.658E-06 4.946E-03 1.671E+02 1.850E+03 -1.042E+01 1.068E-01 1.728E+01 2.874E+02 -1.042E+01












Compound A #DIV/0! #DIV/0! #DIV/0! #DIV/0! 0.000E+00 #DIV/0! 0.000E+00 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! 0.000E+00 1.579E-07 #DIV/0! #DIV/0! 0.000E+00












Compound B #DIV/0! #DIV/0! #DIV/0! #DIV/0! 0.000E+00 #DIV/0! 0.000E+00 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! 0.000E+00 1.579E-07 #DIV/0! #DIV/0! 0.000E+00












Compound C #DIV/0! #DIV/0! #DIV/0! #DIV/0! 0.000E+00 #DIV/0! 0.000E+00 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! 0.000E+00 1.579E-07 #DIV/0! #DIV/0! 0.000E+00












n-Butane (VOC Surrogate) 8.670E+02 1.520E+00 6.824E-06 7.811E-03 1.516E-02 1.063E-01 3.881E+01 1.510E-02 6.824E-06 6.167E-03 8.639E+00 1.983E+02 -1.042E+01 1.226E-04 8.567E+00 1.966E+02 -1.042E+01






































































































Power number (P) 2.251E-04



























Reynolds number (Re) 3.108E+06



























Froude number (Fr) 9.870E+02



























Fraction of area agitated (Vav), ft2 5.379E+03



























F/D 5.642E+00



























Effective Diameter (de) 3.950E+01



























U* 1.335E-01



























WAS VSS, g/m3 15000



























Predicted BOD Removal Effic. 5.717E-01























































































QUALITY CONTROL CHECKS





















Pollutant Influent load, g/s Effluent load, g/s Air emission load, g/s Absorbed load, g/s Biodegradation rate, g/s % Load with effluent % Load air emitted % Biodegraded % Load absorbed Mass balance check


















Methanol 1 0.385 0.006 0.000 0.609 39 1 61 0.00 100


















Benzene 1 0.059 0.292 0.002 0.647 6 29 65 0.21 100


















Carbon disulfide 1 0.064 0.480 0.002 0.454 6 48 45 0.17 100


















Methyl ethyl ketone 1 0.378 0.047 0.000 0.575 38 5 58 0.02 100


















Naphthalene 1 0.097 0.078 0.058 0.767 10 8 77 5.84 100


















Cumene 1 0.033 0.189 0.033 0.746 3 19 75 3.27 100


















Ethylbenzene 1 0.044 0.222 0.016 0.718 4 22 72 1.59 100


















Styrene 1 0.189 0.604 0.043 0.165 19 60 16 4.32 100


















1,3-Butadiene 1 0.067 0.562 0.002 0.369 7 56 37 0.17 100


















Ethylene glycol 1 0.676 0.000 0.000 0.324 68 0 32 0.00 100


















Methyl isobutyl ketone 1 0.228 0.064 0.001 0.707 23 6 71 0.09 100


















Toluene 1 0.040 0.201 0.006 0.753 4 20 75 0.59 100


















Phenol 1 0.010 0.000 0.000 0.990 1 0 99 0.01 100


















n-Hexane 1 0.045 0.321 0.117 0.517 4 32 52 11.74 100


















Cresols (total) 1 0.007 0.000 0.000 0.993 1 0 99 0.00 100


















Xylenes 1 0.049 0.237 0.019 0.695 5 24 69 1.90 100


















Methyl tert-butyl ether 1 0.128 0.151 0.003 0.719 13 15 72 0.27 100


















Biphenyl, 1,1- 1 0.072 0.029 0.108 0.791 7 3 79 10.84 100


















Carbonyl sulfide 1 0.059 0.525 0.000 0.416 6 52 42 0.01 100


















Dichloroethane, 1,2- 1 0.092 0.225 0.001 0.683 9 22 68 0.07 100


















Diethanolamine 1 0.536 0.000 0.000 0.464 54 0 46 0.00 100


















Trimethylpentane, 2,2,4- 1 0.005 0.034 0.902 0.059 1 3 6 90.18 100


















Compound A 1 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!


















Compound B 1 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!


















Compound C 1 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!


















n-Butane (VOC Surrogate) 1 0.047 0.396 0.010 0.547 5 40 55 0.96 100






Sheet 10: Quiescent Unit
This sheet is used for uncovered quiescent tanks and surface impoundments only. Directions: 1) fill-in the input data (yellow boxes); review default variables and constant (yellow boxes) and change if necessary; 2) record air emissions (green boxes); and 3) record effluent concentrations (light blue boxes) for downstream process unit emission calculations.


















CRITICAL INPUTS VALUE UNITS
DEFAULT VARIABLES / CONSTANTS VALUE UNITS DEFAULT VALUE
AIR EMISSIONS VALUE UNITS EFFLUENT WATER CONCENTRATION UNITS









Surface area (A) 20000 m2
Viscosity of water (mL) 0.00893 g/cm-s 0.00893
Methanol 0.006971 g/s 0.260782 g/m3









Temperature (T) 25 deg. C
Density of water (ρL) 1 g/cm3 1
Benzene 0.005109 g/s 0.050379 g/m3









Total pressure (Po) 1 atm
Universal gas constant (R ) 8.21E-05 atm-m3/gmol-K 8.21E-05
Carbon disulfide 0.007658 g/s 0.074281 g/m3









Wastewater flow rate (Q) 0.0876 m3/s
Viscosity of air (ma) 0.000181 g/cm-s 0.000181
Methyl ethyl ketone 0.017050 g/s 0.231466 g/m3









Wastewater depth (D) 4 m
Density of air (ρa) 0.0012 g/cm3 0.0012
Naphthalene 0.005579 g/s 0.068503 g/m3









Biological treatment unit volatile suspended solids (CMLVSS) 50 g/m3
Diffusivity of ether in water (Dether) 8.50E-06 cm2/sec 8.50E-06
Cumene 0.002136 g/s 0.026047 g/m3









Windspeed (U10) 4.47 m/s
Weight fraction of carbon in biomass (foc) 0.33 dimensionless 0.33
Ethylbenzene 0.003076 g/s 0.035277 g/m3









Influent 5-day biochemcial oxygen demand concentration (CBOD5,i) 20 g/m3
Biomass volatile suspend solids yield from influent BOD (Y) 0.67 g VSS/g BOD 0.67
Styrene 0.025931 g/s 0.293861 g/m3









Note: Set CMLVSS = 0 for a non-biologically active unit







1,3-Butadiene 0.009864 g/s 0.090859 g/m3


















Ethylene glycol 0.000007 g/s 0.565836 g/m3


















Methyl isobutyl ketone 0.010723 g/s 0.139796 g/m3









CONSTITUENT INFLUENT CONCENTRATIONS (C0)





Toluene 0.002865 g/s 0.030794 g/m3









Methanol 1.0000 g/m3





Phenol 0.000011 g/s 0.006032 g/m3









Benzene 1.0000 g/m3





n-Hexane 0.004241 g/s 0.048651 g/m3









Carbon disulfide 1.0000 g/m3





Cresols (total) 0.000030 g/s 0.004630 g/m3









Methyl ethyl ketone 1.0000 g/m3





Xylenes 0.003941 g/s 0.040137 g/m3









Naphthalene 1.0000 g/m3





Methyl tert-butyl ether 0.009213 g/s 0.089420 g/m3









Cumene 1.0000 g/m3





Biphenyl, 1,1- 0.004155 g/s 0.050930 g/m3









Ethylbenzene 1.0000 g/m3





Carbonyl sulfide 0.008967 g/s 0.073007 g/m3









Styrene 1.0000 g/m3





Dichloroethane, 1,2- 0.007129 g/s 0.070481 g/m3









1,3-Butadiene 1.0000 g/m3





Diethanolamine 0.000000 g/s 0.418925 g/m3









Ethylene glycol 1.0000 g/m3





Trimethylpentane, 2,2,4- 0.003572 g/s 0.045733 g/m3









Methyl isobutyl ketone 1.0000 g/m3





Compound A #DIV/0! g/s #DIV/0! g/m3









Toluene 1.0000 g/m3





Compound B #DIV/0! g/s #DIV/0! g/m3









Phenol 1.0000 g/m3





Compound C #DIV/0! g/s #DIV/0! g/m3









n-Hexane 1.0000 g/m3





n-Butane (VOC Surrogate) 0.005072 g/s 0.048212 g/m3









Cresols (total) 1.0000 g/m3




















Xylenes 1.0000 g/m3




















Methyl tert-butyl ether 1.0000 g/m3




















Biphenyl, 1,1- 1.0000 g/m3




















Carbonyl sulfide 1.0000 g/m3




















Dichloroethane, 1,2- 1.0000 g/m3




















Diethanolamine 1.0000 g/m3




















Trimethylpentane, 2,2,4- 1.0000 g/m3




















Compound A 1.0000 g/m3




















Compound B 1.0000 g/m3




















Compound C 1.0000 g/m3




















n-Butane (VOC Surrogate) 1.0000 g/m3














































































Windspeed (U10) 4.47 m/s


































































INTERMEDIATE OUTPUTS ScL ScG kl,q kg,q Keq KQ KOL kabs a1 b1 c1












Methanol 5.445E+02 1.006E+00 7.173E-06 8.838E-03 1.859E-04 1.337E-06 1.337E-06 3.080E-08 1.305E+00 3.448E+02 -9.000E+01












Benzene 9.112E+02 1.714E+00 5.089E-06 6.182E-03 2.279E-01 5.070E-06 5.070E-06 2.131E-05 2.158E+00 2.693E+02 -1.357E+01












Carbon disulfide 8.930E+02 1.450E+00 5.158E-06 6.915E-03 1.235E+00 5.155E-06 5.155E-06 1.579E-05 2.177E+00 2.303E+02 -1.712E+01












Methyl ethyl ketone 9.112E+02 1.867E+00 5.089E-06 5.839E-03 2.284E-03 3.683E-06 3.683E-06 3.010E-07 1.841E+00 4.278E+01 -1.000E+01












Naphthalene 1.191E+03 2.556E+00 4.258E-06 4.730E-03 1.973E-02 4.072E-06 4.072E-06 3.618E-04 1.934E+00 6.198E+02 -4.247E+01












Cumene 1.258E+03 1.754E+00 4.105E-06 6.088E-03 5.965E-01 4.100E-06 4.100E-06 6.005E-04 1.944E+00 4.145E+02 -1.080E+01












Ethylbenzene 1.145E+03 2.011E+00 4.370E-06 5.555E-03 3.219E-01 4.360E-06 4.360E-06 2.180E-04 1.998E+00 9.172E+01 -3.238E+00












Styrene 1.116E+03 2.124E+00 4.445E-06 5.354E-03 1.123E-01 4.412E-06 4.412E-06 1.376E-04 2.009E+00 9.615E+02 -2.827E+02












1,3-Butadiene 8.269E+02 6.058E-01 5.429E-06 1.241E-02 3.007E+00 5.428E-06 5.428E-06 1.544E-05 2.240E+00 2.424E+02 -2.205E+01












Ethylene glycol 6.333E+02 9.883E-01 6.485E-06 8.941E-03 7.354E-08 6.574E-10 6.574E-10 1.441E-09 1.000E+00 5.115E+02 -2.898E+02












Methyl isobutyl ketone 1.145E+03 2.011E+00 4.370E-06 5.555E-03 5.639E-03 3.835E-06 3.835E-06 2.446E-06 1.876E+00 1.146E+01 -1.639E+00












Toluene 1.038E+03 1.734E+00 4.664E-06 6.135E-03 2.713E-01 4.651E-06 4.651E-06 8.882E-05 2.063E+00 9.942E+02 -3.062E+01












Phenol 9.813E+02 1.839E+00 4.843E-06 5.897E-03 1.622E-05 9.378E-08 9.378E-08 4.770E-06 1.021E+00 1.237E+03 -7.462E+00












n-Hexane 1.149E+03 7.542E-01 4.359E-06 1.072E-02 4.984E+00 4.359E-06 4.359E-06 1.579E-03 2.016E+00 2.141E+02 -1.042E+01












Cresols (total) 9.602E+02 2.173E+00 4.914E-06 5.273E-03 6.618E-05 3.258E-07 3.258E-07 1.579E-07 1.074E+00 2.922E+02 -1.353E+00












Xylenes 9.561E+02 2.113E+00 4.928E-06 5.374E-03 2.468E-01 4.910E-06 4.910E-06 2.336E-04 2.124E+00 5.647E+02 -2.267E+01












Methyl tert-butyl ether 8.505E+02 1.473E+00 5.328E-06 6.843E-03 2.268E-02 5.151E-06 5.151E-06 1.259E-05 2.176E+00 2.754E+02 -2.464E+01












Biphenyl, 1,1- 1.089E+03 3.733E+00 4.519E-06 3.670E-03 1.144E-02 4.079E-06 4.079E-06 9.089E-04 1.944E+00 2.664E+02 -1.357E+01












Carbonyl sulfide 6.869E+02 9.328E-01 6.143E-06 9.294E-03 2.010E+00 6.141E-06 6.141E-06 9.987E-07 2.402E+00 2.343E+02 -1.712E+01












Dichloroethane, 1,2- 9.020E+02 1.450E+00 5.123E-06 6.915E-03 5.719E-02 5.058E-06 5.058E-06 4.770E-06 2.155E+00 3.025E+01 -2.143E+00












Diethanolamine 9.112E+02 2.143E+00 5.089E-06 5.324E-03 1.581E-09 8.417E-12 8.417E-12 5.868E-09 1.000E+00 1.688E+02 -7.091E+01












Trimethylpentane, 2,2,4- 1.355E+03 2.058E+00 3.906E-06 5.470E-03 1.238E+02 3.906E-06 3.906E-06 1.068E-01 3.323E+00 2.277E+02 -1.042E+01












Compound A #DIV/0! #DIV/0! 0.000E+00 #DIV/0! 0.000E+00 #DIV/0! #DIV/0! 1.579E-07 #DIV/0! #DIV/0! 0.000E+00












Compound B #DIV/0! #DIV/0! 0.000E+00 #DIV/0! 0.000E+00 #DIV/0! #DIV/0! 1.579E-07 #DIV/0! #DIV/0! 0.000E+00












Compound C #DIV/0! #DIV/0! 0.000E+00 #DIV/0! 0.000E+00 #DIV/0! #DIV/0! 1.579E-07 #DIV/0! #DIV/0! 0.000E+00












n-Butane (VOC Surrogate) 8.670E+02 1.520E+00 5.260E-06 6.699E-03 3.881E+01 5.260E-06 5.260E-06 1.226E-04 2.203E+00 2.160E+02 -1.042E+01




















































































F/D 3.989E+01





















Effective Diameter (de) 1.596E+02





















U* 1.335E-01





















Predicted BOD Removal Effic. 1.000E+00





































































QUALITY CONTROL CHECKS















Pollutant Influent load, g/s Effluent load, g/s Air emission load, g/s Absorbed load, g/s Biodegradation rate, g/s % Load with effluent % Load air emitted % Biodegraded % Load absorbed Mass balance check












Methanol 0.0876 0.023 0.007 0.000 0.058 26 8 66 0.00 100












Benzene 0.0876 0.004 0.005 0.000 0.078 5 6 89 0.02 100












Carbon disulfide 0.0876 0.007 0.008 0.000 0.073 7 9 84 0.02 100












Methyl ethyl ketone 0.0876 0.020 0.017 0.000 0.050 23 19 57 0.00 100












Naphthalene 0.0876 0.006 0.006 0.000 0.076 7 6 87 0.38 100












Cumene 0.0876 0.002 0.002 0.000 0.083 3 2 95 0.24 100












Ethylbenzene 0.0876 0.003 0.003 0.000 0.081 4 4 93 0.12 100












Styrene 0.0876 0.026 0.026 0.001 0.036 29 30 41 0.62 101












1,3-Butadiene 0.0876 0.008 0.010 0.000 0.070 9 11 80 0.02 100












Ethylene glycol 0.0876 0.050 0.000 0.000 0.038 57 0 43 0.00 100












Methyl isobutyl ketone 0.0876 0.012 0.011 0.000 0.065 14 12 74 0.01 100












Toluene 0.0876 0.003 0.003 0.000 0.082 3 3 94 0.04 100












Phenol 0.0876 0.001 0.000 0.000 0.087 1 0 99 0.00 100












n-Hexane 0.0876 0.004 0.004 0.001 0.079 5 5 90 1.18 101












Cresols (total) 0.0876 0.000 0.000 0.000 0.087 0 0 100 0.00 100












Xylenes 0.0876 0.004 0.004 0.000 0.080 4 4 91 0.14 100












Methyl tert-butyl ether 0.0876 0.008 0.009 0.000 0.071 9 11 81 0.02 100












Biphenyl, 1,1- 0.0876 0.004 0.004 0.001 0.079 5 5 90 0.71 101












Carbonyl sulfide 0.0876 0.006 0.009 0.000 0.072 7 10 82 0.00 100












Dichloroethane, 1,2- 0.0876 0.006 0.007 0.000 0.074 7 8 85 0.01 100












Diethanolamine 0.0876 0.037 0.000 0.000 0.051 42 0 58 0.00 100












Trimethylpentane, 2,2,4- 0.0876 0.004 0.004 0.065 0.074 5 4 85 74.70 168












Compound A 0.0876 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!












Compound B 0.0876 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!












Compound C 0.0876 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!












n-Butane (VOC Surrogate) 0.0876 0.004 0.005 0.000 0.078 5 6 89 0.09 100

Sheet 11: Chemical Properties
DEFAULT PROPERTIES


Calculated
CAS No. Compound Name Mol.Wt. Vap. Press. (mmHg) H law const. (atm-m3/mol) Di,w (cm2/sec) Di,a (cm2/sec) log(Kow) Kb,max (gVO/g-s) Ks, (g/m3)


Koc
67561 Methanol 32.04 1.26E+02 0.00000455 1.6E-05 1.5E-01 -0.71 0.000005 90


9.33E-02
71432 Benzene 78.11 9.50E+01 0.00557929 9.8E-06 8.8E-02 2.13 5.27777777777778E-06 13.5714285714286


6.46E+01
75150 Carbon disulfide 76.14 3.59E+02 0.03022364 1.0E-05 1.0E-01 2 4.25E-06 17.1219137330841


4.79E+01
78933 Methyl ethyl ketone 72.11 9.53E+01 0.00005590 9.8E-06 8.1E-02 0.28 0.000000555555555555556 10


9.12E-01
91203 Naphthalene 128.17 8.50E-02 0.00048300 7.5E-06 5.9E-02 3.36 0.0000117972222222222 42.47


1.10E+03
98828 Cumene 120.19 4.50E+00 0.01460000 7.1E-06 8.6E-02 3.58 8.63888888888889E-06 10.7966392249193


1.82E+03
100414 Ethylbenzene 106.17 9.60E+00 0.00788000 7.8E-06 7.5E-02 3.14 1.88888888888889E-06 3.23809523809524


6.61E+02
100425 Styrene 104.15 6.12E+00 0.00275000 8.0E-06 7.1E-02 2.94 0.00000863888888888889 282.727272727273


4.17E+02
106990 1,3-Butadiene 54.09 2.11E+03 0.07360000 1.1E-05 2.5E-01 1.99 4.25E-06 22.046017386959


4.68E+01
107211 Ethylene glycol 60.10 1.26E-01 0.00000000 1.4E-05 1.5E-01 -2.04 4.87777777777778E-06 289.76897689769


4.37E-03
108101 Methyl isobutyl ketone 100.16 1.99E+01 0.00013803 7.8E-06 7.5E-02 1.19 0.000000205555555555556 1.6386813840923


7.41E+00
108883 Toluene 92.14 2.84E+01 0.00664000 8.6E-06 8.7E-02 2.75 0.0000204111111111111 30.6166666666667


2.69E+02
108952 Phenol 94.11 2.76E-01 0.00000040 9.1E-06 8.2E-02 1.48 0.0000269444444444444 7.46153846153846


1.45E+01
110543 n-Hexane 86.18 1.51E+02 0.12200000 7.8E-06 2.0E-01 4 0.00000425 10.4196745247811


4.79E+03
1319773 Cresols (total) 108.10 3.00E-01 0.00000162 9.3E-06 6.9E-02 0 6.38888888888889E-06 1.35294117647059


4.79E-01
1330207 Xylenes 106.17 8.04E+00 0.00604124 9.3E-06 7.1E-02 3.17 0.0000113333333333333 22.6666666666667


7.08E+02
1634044 Methyl tert-butyl ether 88.00 1.86E+02 0.00055513 1.1E-05 1.0E-01 1.90 0.00000487777777777778 24.6392510565693


3.81E+01
92524 Biphenyl, 1,1- 154.21 9.64E-03 0.00028000 8.2E-06 4.0E-02 3.76 5.27777777777778E-06 13.5714285714286


2.75E+03
463581 Carbonyl sulfide 60.07 9412 0.04920000 1.30E-05 1.6E-01 0.80 4.2534E-06 17.1219137330841


3.03E+00
107062 Dichloroethane, 1,2- 98.96 79.5 0.00140000 9.90E-06 1.0E-01 1.48 5.833E-07 2.1429


1.45E+01
111422 Diethanolamine 105.14 0.000278 0.00000000 9.80E-06 7.0E-02 -1.43 2.1667E-06 70.9091


1.78E-02
540841 Trimethylpentane, 2,2,4- 114.23 49.172 3.03000000 6.59E-06 7.3E-02 5.83 0.00000425 10.4196745247811


3.24E+05

Compound A










4.79E-01

Compound B










4.79E-01

Compound C










4.79E-01
106978 n-Butane (VOC Surrogate) 58.12 1.82E+03 0.95000000 1.03E-05 9.9E-02 2.89 0.00000425 10.4196745247811


3.72E+02




























Color Code:













Data not in HWIR database; used value from CHEMDAT8 constituent input database












Biodegradation reactions are the same as other aromatic hydrocarbons: oxygenase addition of molecular oxygen to one of the aromatic rings (Boyle, 1992). Therefore, the known values for Benzene were substituted.












Biodegradation reactions are the same as other aliphatic compounds (McCarty and Rittman, 2001). Therefore, the known biodegradation constants for n-Hexane were substituted.

Biodegradation reactions are the same as other alcohols (Rittman and McCarty, 2001). Therefore, the known diodegradation constants for Butanol were substituted.

Substituted Carbon disulfide biodegradation constants.



















SITE-SPECIFIC PROPERTIES



CAS No. Compound Name Mol.Wt. Vap. Press. (mmHg) H law const. (atm-m3/mol) Di,w (cm2/sec) Di,a (cm2/sec) log(Kow) Kb,max (gVO/g-s) Ks, (g/m3)



67561 Methanol











71432 Benzene











75150 Carbon disulfide











78933 Methyl ethyl ketone











91203 Naphthalene











98828 Cumene











100414 Ethylbenzene











100425 Styrene











106990 1,3-Butadiene











107211 Ethylene glycol











108101 Methyl isobutyl ketone











108883 Toluene











108952 Phenol











110543 n-Hexane











1319773 Cresols (total)











1330207 Xylenes











1634044 Methyl tert-butyl ether











92524 Biphenyl, 1,1-











463581 Carbonyl sulfide











107062 Dichloroethane, 1,2-











111422 Diethanolamine











540841 Trimethylpentane, 2,2,4-












Compound A












Compound B












Compound C











106978 n-Butane (VOC Surrogate)





















































References:












Boyle, A.W., et al. (1992). "Bacterial PCB Biodegradation." Biodegradation 3(2/3), pp. 285-298.












Rittman, B.E. and McCarty, P.L. (2001). "Environmental Biotechnology: Principles and Applications". McGraw-Hill, New York, NY.






























































































































































































































































































































































































































































































































































































































































































































































































































































































































































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