Download:
pdf |
pdfAPPENDIX C – ALLOCATION OF LABEL ELEMENTS (MANDATORY)
C.1
The label for each hazardous chemical shall include the product identifier used on
the safety data sheet
C.1.1
The labels on shipped containers shall also include the name, address, and
telephone number of the manufacturer, importer, or responsible party.
C.2
The label for each hazardous chemical that is classified shall include the signal
word, hazard statement(s), pictogram(s), and precautionary statement(s) specified in C.4 for each
hazard class and associated hazard category, except as provided for in C.2.1 through C.2.4. For
unclassified hazards, the label shall include a description of the hazards and appropriate
precautions for safe handling and use under supplementary information.
C.2.1
Precedence of hazard information
C.2.1.1
appear;
If the signal word “Danger” is included, the signal word “Warning” shall not
C.2.1.2
If the skull and crossbones pictogram is included, the exclamation mark
pictogram shall not appear where it is used for acute toxicity;
C.2.1.3
If the corrosive pictogram is included, the exclamation mark pictogram shall not
appear where it is used for skin or eye irritation;
C.2.1.4
If the health hazard pictogram is included for respiratory sensitization, the
exclamation mark pictogram shall not appear where it is used for skin sensitization or for skin or
eye irritation.
C.2.2
Hazard statement text
C.2.2.1
The text of all applicable hazard statements shall appear on the label, except as
otherwise specified. The information in italics shall be included as part of the hazard statement
as provided. For example: “causes damage to organs (state all organs affected) through
prolonged or repeated exposure (state route of exposure if no other routes of exposure cause the
hazard)”. Hazard statements may be combined where appropriate to reduce the information on
the label and improve readability, as long as all of the hazards are conveyed as required.
C.2.3
Pictograms
C.2.3.1
Pictograms shall be in the shape of a square set at a point and shall include a black
hazard symbol on a white background with a red frame sufficiently wide to be clearly visible.
C.2.3.2
One of eight standard hazard symbols shall be used in each pictogram. The eight
hazard symbols are depicted in Figure C.1. A pictogram using the exclamation mark symbol is
presented in Figure C.2, for the purpose of illustration.
1
Figure C.1 – Hazard Symbols and Classes
Flame
Flame Over Circle
Flammables
Oxidizers
Self Reactives
Pyrophorics
Self-heating
Exploding Bomb
Irritant
Explosives
Dermal Sensitizer
Self Reactives
Acute Toxicity
(harmful)
Organic Peroxides
Narcotic Effects
Emits Flammable Gas
Respiratory Tract
Irritation
Organic Peroxides
Corrosion
Exclamation Mark
Gas Cylinder
Health Hazard
Skull and Crossbones
Carcinogen
Corrosives
Gases Under Pressure
Respiratory Sensitizer
Reproductive Toxicity
Target Organ Toxicity
Mutagenicity
Aspiration Toxicity
2
Acute Toxicity (severe)
Figure C.2 – Exclamation Mark Pictogram
C.2.3.3
Where a label required by the Department of Transportation under Title 49 of the
Code of Federal Regulations appears on a container, the pictogram specified in C.4 for the same
hazard shall not appear.
C.2.4
Precautionary statement text
C.2.4.1
There are four types of precautionary statements presented, “prevention,”
“response,” “storage,” and “disposal.” The core part of the precautionary statement is presented
in bold print. This is the text, except as otherwise specified, that shall appear on the label. Where
additional information is required, it is indicated in plain text.
C.2.4.2
When a backslash or diagonal mark [/] appears in the precautionary statement
text, it indicates that a choice has to be made between the separated phrases. In such cases, the
manufacturer, importer, or responsible party can choose the most appropriate phrase(s). For
example, “Wear protective gloves/protective clothing/eye protection/face protection” could read
“wear eye protection”.
C.2.4.3
When three full stops […] appear in the precautionary statement text, they
indicate that all applicable conditions are not listed. For example, in “Use explosion-proof
electrical/ventilating/lighting/.../equipment”, the use of “...” indicates that other equipment may
need to be specified. In such cases, the manufacturer, importer, or responsible party can choose
the other conditions to be specified.
C.2.4.4
When text in italics is used in a precautionary statement, this indicates specific
conditions applying to the use or allocation of the precautionary statement. For example, “Use
explosion-proof electrical/ventilating/lighting/.../equipment” is only required for flammable
solids “if dust clouds can occur”. Text in italics is intended to be an explanatory, conditional note
and is not intended to appear on the label.
C.2.4.5
Precautionary statements may be combined or consolidated to save label space
and improve readability. For example, “Keep away from heat, sparks and open flame,” “Store in
3
a well-ventilated place” and “Keep cool” can be combined to read “Keep away from heat, sparks
and open flame and store in a cool, well-ventilated place”.
C.2.4.6
In most cases, the precautionary statements are independent (e.g., the phrases for
explosive hazards do not modify those related to certain health hazards and products that are
classified for both hazard classes shall bear appropriate precautionary statements for both).
Where a chemical is classified for a number of hazards, and the precautionary statements are
similar, the most stringent shall be included on the label (this will be applicable mainly to
preventive measures). An order of precedence may be imposed by the manufacturer, importer or
responsible party in situations where phrases concern “Response.” Rapid action may be crucial.
For example, if a chemical is carcinogenic and acutely toxic, rapid action may be crucial, and
first aid measures for acute toxicity will take precedence over those for long term effects. In
addition, medical attention to delayed health effects may be required in cases of incidental
exposure, even if not associated with immediate symptoms of intoxication.
C.3
Supplementary hazard information
C.3.1
To ensure that non-standardized information does not lead to unnecessarily wide
variation or undermine the required information, supplementary information on the label is
limited to when it provides further detail and does not contradict or cast doubt on the validity of
the standardized hazard information, or when it provides information about unclassified hazards.
C.3.2
Where the manufacturer, importer, or distributor chooses to add supplementary
information on the label, the placement of supplemental information shall not impede
identification of information required by this section.
C.3.3
Where an ingredient with unknown acute toxicity is used in a mixture at a
concentration ≥ 1%, a statement that × percent of the mixture consists of ingredient(s) of
unknown toxicity is required on the label.
4
C.4 REQUIREMENTS FOR SIGNAL WORDS, HAZARD STATEMENTS, PICTOGRAMS, AND PRECAUTIONARY
STATEMENTS
C. 4.1 ACUTE TOXICITY - ORAL
(CLASSIFIED IN ACCORDANCE with appendix A.1)
Pictogram
Skull and crossbones
Hazard category
Signal word
Hazard statement
1
Danger
Fatal if swallowed
2
Danger
Fatal if swallowed
Precautionary statements
Prevention
Wash …thoroughly after handling.
… Manufacturer, importer, or distributor
to specify parts of the body to be washed
after handling.
Do not eat, drink or smoke when using
this product.
Response
Storage
If swallowed: Immediately call a
poison center or doctor/physician.
Specific treatment (see … on this label)
… Reference to supplemental first aid
instruction.
- if immediate administration of antidote
is required.
Rinse mouth.
5
Store locked up.
Disposal
Dispose of contents/container to…
... in accordance with
local/regional/national/international
regulations (to be specified).
C.4.1 ACUTE TOXICITY – ORAL (CONTINUED)
(CLASSIFIED IN ACCORDANCE with Appendix A.1)
Pictogram
Skull and crossbones
Hazard category
Signal word
Hazard statement
3
Danger
Toxic if swallowed
Precautionary statements
Prevention
Wash … thoroughly after handling.
… Manufacturer, importer, or distributor
to specify parts of the body to be washed
after handling.
Do not eat, drink or smoke when using
this product.
Response
Storage
If swallowed: Immediately call a
poison center or doctor/physician.
Specific treatment (see ... on this label)
... Reference to supplemental first aid
instruction.
- if immediate administration of antidote
is required.
Rinse mouth.
6
Store locked up.
Disposal
Dispose of contents/container to...
... in accordance with
local/regional/national/international
regulations (to be specified).
C.4.1 ACUTE TOXICITY – ORAL (CONTINUED)
(CLASSIFIED IN ACCORDANCE with appendix A.1)
Pictogram
Exclamation mark
Hazard category
Signal word
Hazard statement
4
Warning
Harmful if swallowed
Precautionary statements
Prevention
Wash … thoroughly after handling.
… Manufacturer, importer, or distributor
to specify parts of the body to be washed
after handling.
Response
Storage
If swallowed: Call a poison center or
doctor/physician if you feel unwell.
Rinse mouth.
Do not eat, drink or smoke when using
this product.
7
Disposal
Dispose of contents/container to...
... in accordance with
local/regional/national/international
regulations (to be specified).
C.4.2 ACUTE TOXICITY - DERMAL
(CLASSIFIED IN ACCORDANCE with Appendix A.1)
Pictogram
Skull and crossbones
Hazard category
Signal word
Hazard statement
1
Danger
Fatal in contact with skin
2
Danger
Fatal in contact with skin
Precautionary statements
Prevention
Response
Storage
Do not get in eyes, on skin, or on
clothing.
If on skin: Gently wash with plenty of
soap and water.
Wash … thoroughly after handling.
… Manufacturer, importer, or distributor
to specify parts of the body to be washed
after handling.
Immediately call a poison center or
doctor/physician.
Do not eat, drink or smoke when using
this product.
Wear protective gloves/protective
clothing.
Manufacturer, importer, or distributor to
specify type of equipment.
Specific measures (see ... on this label)
... Reference to supplemental first aid
instruction.
- if immediate measures such as specific
cleansing agent is advised.
Remove/Take off immediately all
contaminated clothing.
Wash contaminated clothing before
reuse.
8
Store locked up.
Disposal
Dispose of contents/container to...
... in accordance with
local/regional/national/international
regulations (to be specified).
C.4.2 ACUTE TOXICITY – DERMAL (CONTINUED)
(CLASSIFIED IN ACCORDANCE with appendix A.1)
Pictogram
Skull and crossbones
Hazard category
Signal word
Hazard statement
3
Danger
Toxic in contact with skin
Precautionary statements
Prevention
Wear protective gloves/protective
clothing.
Manufacturer, importer, or distributor to
specify type of equipment.
Response
Storage
If on skin: Wash with plenty of soap
and water.
Call a poison center or
doctor/physician if you feel unwell.
Specific measures (see ... on this label)
... Reference to supplemental first aid
instruction.
- if measures such as specific cleansing
agent is advised.
Remove/Take off immediately all
contaminated clothing.
Wash contaminated clothing before
reuse.
9
Store locked up.
Disposal
Dispose of contents/container to...
... in accordance with
local/regional/national/international
regulations (to be specified).
C.4.2 ACUTE TOXICITY – DERMAL (CONTINUED)
(CLASSIFIED IN ACCORDANCE with appendix A.1)
Pictogram
Exclamation mark
Hazard category
Signal word
Hazard statement
4
Warning
Harmful in contact with skin
Precautionary statements
Prevention
Wear protective gloves/protective
clothing
Manufacturer, importer, or distributor to
specify type of equipment.
Response
Storage
If on skin: Wash with plenty of soap
and water.
Call a poison center or
doctor/physician if you feel unwell.
Specific measures (see ... on this label)
... Reference to supplemental first aid
instruction.
- if measures such as specific cleansing
agent is advised.
Wash contaminated clothing before
reuse.
10
Disposal
Dispose of contents/container to...
... in accordance with
local/regional/national/international
regulations (to be specified).
C.4.3 ACUTE TOXICITY - INHALATION
(CLASSIFIED IN ACCORDANCE with appendix A.1)
Pictogram
Skull and crossbones
Hazard category
Signal word
Hazard statement
1
Danger
Fatal if inhaled
2
Danger
Fatal if inhaled
Precautionary statements
Prevention
Do not breathe dust/fume/gas/mist/
vapors/spray.
Manufacturer, importer, or distributor to
specify applicable conditions.
Use only outdoors or in a wellventilated area.
Wear respiratory protection.
Manufacturer, importer, or distributor to
specify equipment.
Response
Storage
If inhaled: Remove victim to fresh air
and keep at rest in a position
comfortable for breathing.
Immediately call a poison center or
doctor/physician.
Specific treatment is urgent (see ... on
this label)
... Reference to supplemental first aid
instruction.
- if immediate administration of
antidote is required.
11
Store in a wellventilated place. Keep
container tightly
closed.
- if product is volatile
as to
generate
hazardous atmosphere.
Store locked up.
Disposal
Dispose of contents/container to...
... in accordance with
local/regional/national/international
regulations (to be specified).
C.4.3 ACUTE TOXICITY – INHALATION (CONTINUED)
(CLASSIFIED IN ACCORDANCE with appendix A.1)
Pictogram
Skull and crossbones
Hazard category
Signal word
Hazard statement
3
Danger
Toxic if inhaled
Precautionary statements
Prevention
Avoid breathing dust/fume/gas/mist/
vapors/spray.
Manufacturer, importer, or distributor to
specify applicable conditions.
Use only outdoors or in a wellventilated area.
Response
Storage
If inhaled: Remove victim to fresh air
and keep at rest in a position
comfortable for breathing.
Call a poison center or
doctor/physician.
Specific treatment (see ... on this label)
... Reference to supplemental first aid
instruction.
- if immediate specific measures are
required.
12
Store in a wellventilated place. Keep
container tightly
closed.
- if product is volatile
so as to generate
hazardous atmosphere.
Store locked up.
Disposal
Dispose of content/container to…
… in accordance with
local/regional/national/international
regulations (to be specified).
C.4.3 ACUTE TOXICITY – INHALATION (CONTINUED)
(CLASSIFIED IN ACCORDANCE with appendix A.1)
Pictogram
Exclamation mark
Hazard category
Signal word
Hazard statement
4
Warning
Harmful if inhaled
Precautionary statements
Prevention
Avoid breathing dust/fume/gas/mist/
vapors/spray.
Manufacturer, importer, or distributor to
specify applicable conditions.
Use only outdoors or in a wellventilated area.
Response
Storage
If inhaled: Remove victim to fresh air
and keep at rest in a position
comfortable for breathing.
Call a poison center or
doctor/physician if you feel unwell.
13
Disposal
C.4.4 SKIN CORROSION/IRRITATION
(CLASSIFIED IN ACCORDANCE with appendix A.2)
Pictogram
Corrosion
Hazard category
1A to 1C
Signal word
Danger
Hazard statement
Causes severe skin burns and eye damage
Precautionary statements
Prevention
Do not breathe dusts or mists.
- if inhalable particles of dusts or
mists may occur during use.
Wash …thoroughly after
handling.
…Manufacturer, importer, or
distributor to specify parts of the
body to be washed after handling.
Wear protective
gloves/protective clothing/eye
protection/face protection.
Manufacturer, importer, or
distributor to specify type of
equipment.
Response
If swallowed: Rinse mouth. Do NOT induce vomiting.
If on skin (or hair): Remove/Take off immediately all
contaminated clothing. Rinse skin with water/shower.
Wash contaminated clothing before reuse.
If inhaled: Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
Immediately call a poison center or doctor/physician.
Specific treatment (see ... on this label)
... Reference to supplemental first aid instruction.
- Manufacturer, importer, or distributor may specify a cleansing agent
if appropriate.
If in eyes: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
14
Storage
Store
locked
up.
Disposal
Dispose of contents/container
to...
... in accordance with
local/regional/national/internatio
nal regulations (to be specified).
C.4.4 SKIN CORROSION/IRRITATION (CONTINUED)
(CLASSIFIED IN ACCORDANCE with appendix A.2)
Pictogram
Exclamation mark
Hazard category
Signal word
Hazard statement
2
Warning
Causes skin irritation
Precautionary statements
Prevention
Wash … thoroughly after handling.
… Manufacturer, importer, or distributor
to specify parts of the body to be washed
after handling.
Wear protective gloves.
Manufacturer, importer, or distributor to
specify type of equipment.
Response
Storage
If on skin: Wash with plenty of soap
and water.
Specific treatment (see ... on this label)
... Reference to supplemental first aid
instruction.
- Manufacturer, importer, or distributor
may specify a cleansing agent if
appropriate.
If skin irritation occurs: Get medical
advice/attention.
Take off contaminated clothing and
wash before reuse.
15
Disposal
C.4.5 EYE DAMAGE/IRRITATION
(CLASSIFIED IN ACCORDANCE with appendix A.3)
Pictogram
Corrosion
Hazard category
Signal word
Hazard statement
1
Danger
Causes serious eye damage
Precautionary statements
Prevention
Wear eye protection/face
protection.
Manufacturer, importer, or
distributor to specify type of
equipment.
Response
Storage
If in eyes: Rinse cautiously with water
for several minutes. Remove contact
lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center or
doctor/physician.
16
Disposal
C.4.5 EYE DAMAGE/IRRITATION (CONTINUED)
(CLASSIFIED IN ACCORDANCE with appendix A.3)
Pictogram
Exclamation mark
Hazard category
Signal word
Hazard statement
2A
Warning
Causes serious eye irritation
Precautionary statements
Prevention
Response
Storage
Wash … thoroughly after handling.
… Manufacturer, importer, or distributor
to specify parts of the body to be washed
after handling.
If in eyes: Rinse cautiously with water
for several minutes. Remove contact
lenses, if present and easy to do.
Continue rinsing.
Wear eye protection/face protection.
Manufacturer, importer, or distributor to
specify type of equipment.
If eye irritation persists: Get medical
advice/attention.
17
Disposal
C.4.5 EYE DAMAGE/IRRITATION (CONTINUED)
(CLASSIFIED IN ACCORDANCE with appendix A.3)
Pictogram
No Pictogram
Hazard category
Signal word
Hazard statement
2B
Warning
Causes eye irritation
Precautionary statements
Prevention
Wash … thoroughly after handling.
… Manufacturer, importer, or distributor
to specify parts of the body to be washed
after handling.
Response
Storage
If in eyes: Rinse cautiously with water
for several minutes. Remove contact
lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical
advice/attention.
18
Disposal
C.4.6 SENSITIZATION - RESPIRATORY
(CLASSIFIED IN ACCORDANCE with appendix A.4)
Pictogram
Health hazard
Hazard category
Signal word
Hazard statement
1 (including both subcategories 1A and
1B)
Danger
May cause allergy or asthma symptoms or breathing difficulties if
inhaled
Precautionary statements
Prevention
Response
Storage
Avoid breathing dust/fume/gas/mist/
vapors/spray.
Manufacturer, importer, or distributor to
specify applicable conditions.
If inhaled: If breathing is difficult,
remove victim to fresh air and keep at
rest in a position comfortable for
breathing.
In case of inadequate ventilation wear
respiratory protection.
Manufacturer, importer, or distributor to
specify equipment
If experiencing respiratory symptoms:
Call a poison center or
doctor/physician.
19
Disposal
Dispose of contents/container to...
... in accordance with
local/regional/national/international
regulations (to be specified).
C.4.7 SENSITIZATION - SKIN
(CLASSIFIED IN ACCORDANCE with appendix A.4)
Pictogram
Exclamation mark
Hazard category
Signal word
Hazard statement
1 (including both subcategories 1A and 1B)
Warning
May cause an allergic skin reaction
Precautionary statements
Prevention
Avoid breathing dust/fume/gas/mist/
vapors/spray.
Manufacturer, importer, or distributor to
specify applicable conditions.
Contaminated work clothing must not
be allowed out of the workplace.
Wear protective gloves.
Manufacturer, importer, or distributor to
specify type of equipment.
Response
Storage
If on skin: Wash with plenty of soap
and water.
If skin irritation or rash occurs: Get
medical advice/attention.
Specific treatment (see ... on this label)
... Reference to supplemental first aid
instruction.
- Manufacturer, importer, or distributor
may specify a cleansing agent if
appropriate.
Wash contaminated clothing before
reuse.
20
Disposal
Dispose of contents/container to...
... in accordance with
local/regional/national/international
regulations (to be specified).
C.4.8 GERM CELL MUTAGENICITY
(CLASSIFIED IN ACCORDANCE with appendix A.5)
Pictogram
Health hazard
Hazard statement
Hazard category
Signal word
1A and 1B
Danger
May cause genetic defects <...>
2
Warning
Suspected of causing genetic defects <...>
(state route of exposure if no other routes of exposure cause the
hazard)
Precautionary statements
Prevention
Obtain special instructions before use.
Response
Storage
If exposed or concerned: Get medical
advice/attention.
Do not handle until all safety
precautions have been read and
understood.
Use personal protective equipment as
required.
21
Store locked up.
Disposal
Dispose of contents/container to...
... in accordance with
local/regional/national/international
regulations (to be specified).
C.4.9 CARCINOGENICITY
(CLASSIFIED IN ACCORDANCE with appendix A.6)
Pictogram
Health hazard
Hazard category
Signal word
Hazard statement
1A and 1B
Danger
May cause cancer <...>
2
Warning
Suspected of causing cancer <...>
(state route of exposure if no other routes of exposure cause the hazard).
Precautionary statements
Prevention
Obtain special instructions before use.
Response
Storage
If exposed or concerned: Get medical
advice/attention.
Do not handle until all safety
precautions have been read and
understood.
Store locked up.
Disposal
Dispose of contents/container to...
... in accordance with
local/regional/national/international
regulations (to be specified).
Use personal protective equipment as
required.
NOTE: If a Category 2 carcinogen ingredient is present in the mixture at a concentration between 0.1% and 1%, information is required on the SDS for a
product; however, a label warning is optional. If a Category 2 carcinogen ingredient is present in the mixture at a concentration of ≥ 1%, both an SDS and a label
is required and the information must be included on each.
22
C.4.10 TOXIC TO REPRODUCTION
(CLASSIFIED IN ACCORDANCE with appendix A.7)
Pictogram
Health hazard
Hazard category
1A and 1B
2
Signal word
Danger
Warning
Hazard statement
May damage fertility or the unborn child <...> <<...>>
Suspected of damaging fertility or the unborn child <...> <<...>>
(state specific effect if known)
(state route of exposure if no other routes of exposure cause the hazard)
Precautionary statements
Prevention
Obtain special instructions before use.
Response
Storage
If exposed or concerned: Get medical
advice/attention.
Do not handle until all safety
precautions have been read and
understood.
Use personal protective equipment as
required.
23
Store locked up.
Disposal
Dispose of contents/container to...
... in accordance with
local/regional/national/international
regulations (to be specified).
C.4.10 TOXIC TO REPRODUCTION (CONTINUED)
(CLASSIFIED IN ACCORDANCE with appendix A.7)
(EFFECTS ON OR VIA LACTATION)
Pictogram
No Pictogram
Hazard category
Signal word
Hazard statement
No designated number
No signal word
May cause harm to breast-fed children
(See Table A.7.1 in
Appendix A.7)
Precautionary statements
Prevention
Obtain special instructions before use.
Response
Storage
If exposed or concerned: Get medical
advice/attention.-
Do not breathe dusts or mists.
- if inhalable particles of dusts or mists
may occur during use.
Avoid contact during pregnancy/while
nursing.
Wash … thoroughly after handling.
…Manufacturer, importer, or distributor
to specify parts of the body to be washed
after handling.
Do not eat, drink or smoke when using
this product.
24
Disposal
C.4.11 SPECIFIC TARGET ORGAN TOXICITY (Single Exposure)
(CLASSIFIED IN ACCORDANCE with appendix A.8)
Pictogram
Health hazard
Hazard category
Signal word
Hazard statement
1
Danger
Causes damage to organs <...> <<...>>
(or state all organs affected if known)
(state route of exposure if no other routes of exposure cause the hazard)
Precautionary statements
Prevention
Do not breathe dust/fume/gas/mist/
vapors/spray.
Manufacturer, importer, or distributor to
specify applicable conditions.
Wash …thoroughly after handling.
… Manufacturer, importer, or distributor
to specify parts of the body to be washed
after handling.
Response
Storage
If exposed: Call a poison center or
doctor/physician.
Specific treatment (see ... on this label)
... Reference to supplemental first aid
instruction.
- if immediate measures are required.
Do not eat, drink or smoke when
using this product.
25
Store locked up.
Disposal
Dispose of contents/container to...
... in accordance with
local/regional/national/international
regulations (to be specified).
C.4.11 SPECIFIC TARGET ORGAN TOXICITY (Single Exposure) (CONTINUED)
(CLASSIFIED IN ACCORDANCE with appendix A.8)
Pictogram
Health hazard
Hazard category
2
Signal word
Warning
Hazard statement
May cause damage to organs <...> <<...>>
(or state all organs affected, if known)
(state route of exposure if no other routes of exposure cause the hazard)
Precautionary statements
Prevention
Do not breathe dust/fume/gas/mist/
vapors/spray.
Manufacturer, importer, or distributor to
specify applicable conditions.
Response
Storage
If exposed or if you feel unwell: Call a
poison center or doctor/physician.
Wash … thoroughly after handling.
… Manufacturer, importer, or distributor
to specify parts of the body to be washed
after handling.
Do not eat, drink or smoke when using
this product.
26
Store locked up.
Disposal
Dispose of contents/container to...
... in accordance with
local/regional/national/international
regulations (to be specified).
C.4.11 SPECIFIC TARGET ORGAN TOXICITY (Single Exposure)(CONTINUED)
(CLASSIFIED IN ACCORDANCE with appendix A.8)
Pictogram
Exclamation mark
Hazard category
Signal word
Hazard statement
3
Warning
May cause respiratory irritation; or
May cause drowsiness or dizziness
Precautionary statements
Prevention
Avoid breathing dust/fume/gas/mist/
vapors/spray.
Manufacturer, importer, or distributor to
specify applicable conditions.
Use only outdoors or in a wellventilated area.
Response
Storage
If Inhaled: Remove victim to fresh air
and keep at rest in a position
comfortable for breathing.
Call a poison center or
doctor/physician if you feel unwell.
Store in a wellventilated place. Keep
container tightly
closed.
- if product is volatile
so as to generate
hazardous atmosphere.
Store locked up.
27
Disposal
Dispose of contents/container to...
... in accordance with
local/regional/national/international
regulations (to be specified).
C.4.12 SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure)
(CLASSIFIED IN ACCORDANCE with appendix A.9)
Pictogram
Health hazard
Hazard category
1
Signal word
Danger
Hazard statement
Causes damage to organs <...> through prolonged or repeated exposure
<<...>>
(state all organs affected, if known)
(state route of exposure if no other routes of exposure cause the
hazard)
Precautionary statements
Prevention
Do not breathe dust/fume/gas/mist/
vapors/spray.
Manufacturer, importer, or distributor to
specify applicable conditions.
Response
Storage
Get medical advice/attention if you feel
unwell.
Wash … thoroughly after handling.
…Manufacturer, importer, or distributor
to specify parts of the body to be washed
after handling.
Do not eat, drink or smoke when using
this product.
28
Disposal
Dispose of contents/container to...
... in accordance with
local/regional/national/international
regulations (to be specified).
C.4.12 SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure) (CONTINUED)
(CLASSIFIED IN ACCORDANCE with appendix A.9)
Pictogram
Health hazard
Hazard category
2
Signal word
Warning
Hazard statement
May cause damage to organs <...> through prolonged or repeated
exposure <<...>>
(state all organs affected, if known)
(state route of exposure if no other routes of exposure cause the
hazard)
Precautionary statements
Prevention
Do not breathe dust/fume/gas/mist/
vapors/spray.
Manufacturer, importer, or distributor to
specify applicable conditions.
Response
Storage
Get medical advice/attention if you feel
unwell.
29
Disposal
Dispose of contents/container to...
... in accordance with
local/regional/national/international
regulations (to be specified).
C.4.13 ASPIRATION HAZARD
(CLASSIFIED IN ACCORDANCE with appendix A.10)
Pictogram
Health hazard
Hazard category
Signal word
Hazard statement
1
Danger
May be fatal if swallowed and enters airways
Precautionary statements
Prevention
Response
Storage
If Swallowed: Immediately call a
poison center or doctor/physician.
Do NOT induce vomiting.
30
Store locked up.
Disposal
Dispose of contents/container to...
... in accordance with
local/regional/national/international
regulations (to be specified).
C.4.14 EXPLOSIVES
(CLASSIFIED IN ACCORDANCE with Appendix B.1)
Pictogram
Exploding bomb
Hazard category
Signal word
Hazard statement
Unstable explosive
Danger
Unstable explosive
Precautionary statements
Prevention
Response
Storage
Obtain special instructions before use.
Explosion risk in case of fire.
Do not handle until all safety
precautions have been read and
understood.
Do NOT fight fire when fire reaches
explosives.
Evacuate area.
Use personal protective equipment as
required.
31
Store ...
…in accordance with
local/regional/
national/international
regulations (to be
specified).
Disposal
Dispose of contents/container
to ...
…in accordance with local/regional/
national/international regulations (to be
specified).
C.4.14 EXPLOSIVES (Continued)
(CLASSIFIED IN ACCORDANCE with Appendix B.1)
Pictogram
Exploding bomb
Hazard category
Division 1.1
Division 1.2
Division 1.3
Signal word
Danger
Danger
Danger
Hazard statement
Explosive; mass explosion hazard
Explosive; severe projection hazard
Explosive; fire, blast or projection hazard
Precautionary statements
Prevention
Response
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Manufacturer, importer, or distributor to specify applicable ignition source(s).
In case of fire:
evacuate area.
Keep wetted with...
… Manufacturer, importer, or distributor to specify appropriate material.
if drying out increases explosion hazard, except as needed for manufacturing
or operating processes (e.g. nitrocellulose).
Explosion risk in case
of fire.
Storage
Disposal
Store ...
…in accordance with
local/regional/national/
international
regulations (to be
specified).
Dispose of
contents/container to ...
… in accordance with
local/ regional/national/
international regulations
(to be specified).
Do NOT fight fire
when fire reaches
explosives.
Ground/bond container and receiving equipment.
- if the explosive is electrostatically sensitive.
Do not subject to grinding/shock/…/friction.
…Manufacturer, importer, or distributor to specify applicable rough handling.
Wear face protection.
Manufacturer, importer, or distributor to specify type of equipment.
Note: Unpackaged explosives or explosives repacked in packagings other than the original or similar packaging shall have the label elements assigned to
Division 1.1 unless the hazard is shown to correspond to one of the hazard categories in Appendix B.1, in which case the corresponding symbol, signal
word and/or the hazard statement shall be assigned
32
C.4.14 EXPLOSIVES (Continued)
(CLASSIFIED IN ACCORDANCE with Appendix B.1)
Pictogram
Exploding bomb 1
Hazard category
Division 1.4
Signal word
Warning
Hazard statement
Fire or projection hazard
Precautionary statements1
Prevention
Response
Storage
Disposal
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Manufacturer, importer, or distributor to specify applicable ignition
source(s).
In case of fire: Evacuate area.
Store ...
…in accordance
with local/regional/
national/internation
al regulations (to
be specified).
Dispose of
contents/container
to...
… in accordance with
local/regional/national/i
nternational regulations
(to be specified).
Ground/bond container and receiving equipment.
- if the explosive is electrostatically sensitive.
Do not subject to grinding/shock/…/friction.
Manufacturer, importer, or distributor to specify applicable rough
handling.
Wear face protection.
Manufacturer, importer, or distributor to specify type of equipment.
1
Explosion risk in case of fire.
- except if explosives are 1.4S
ammunition and components
thereof.
Do NOT fight fire when fire
reaches explosives.
Fight fire with normal
precautions from a reasonable
distance
- if explosives are 1.4S
ammunition and components
thereof.
Except if explosives are 1.4S small arms ammunition and components thereof. Labels for 1.4S small arms ammunition and components shall include appropriate precautionary
statements.
33
Note: Unpackaged explosives or explosives repacked in packagings other than the original or similar packaging shall have the label elements assigned to Division 1.1 unless the
hazard is shown to correspond to one of the hazard categories in Appendix B.1, in which case the corresponding symbol, signal word and/or the hazard statement shall be assigned1
34
C.4.14 EXPLOSIVES (CONTINUED)
(CLASSIFIED IN ACCORDANCE with Appendix B.1)
Pictogram
No pictogram
Hazard category
Division 1.5
Signal word
Danger
Hazard statement
May mass explode in fire
Precautionary statements
Prevention
Keep away from heat/sparks/open
flames/hot surfaces. - No smoking.
Manufacturer, importer, or distributor to
specify applicable ignition source(s).
Keep wetted with...
… Manufacturer, importer, or distributor to
specify appropriate material.
if drying out increases explosion hazard,
except as needed for manufacturing or
operating processes (e.g. nitrocellulose).
Response
In case of fire: Evacuate
area.
Explosion risk in case of
fire.
Storage
Disposal
Store ...
…in accordance with
local/regional/
national/international regulations
(to be specified).
Dispose of contents/container to ...
… in accordance with local/regional/
national/international regulations (to be
specified).
Do NOT fight fire when
fire reaches explosives.
Ground/bond container and receiving
equipment
- if the explosive is electrostatically sensitive.
Do not subject to grinding/shock/…/friction.
…Manufacturer, importer, or distributor to
specify applicable rough handling.
Wear face protection.
Manufacturer, importer, or distributor to
specify type of equipment.
Note: Unpackaged explosives or explosives repacked in packagings other than the original or similar packaging shall have the label elements assigned to
Division 1.1 unless the hazard is shown to correspond to one of the hazard categories in Appendix B.1, in which case the corresponding symbol, signal
word
and/or
the
hazard
statement
shall
be
assigned
35
C.4.14 EXPLOSIVES (CONTINUED)
(CLASSIFIED IN ACCORDANCE with Appendix B.1)
Pictogram
No pictogram
Hazard category
Division 1.6
Signal word
No signal word
Hazard statement
No hazard statement
Precautionary statements
Prevention
None assigned.
Response
Storage
None assigned
None assigned
Disposal
None assigned
Note: Unpackaged explosives or explosives repacked in packagings other than the original or similar packaging shall have the label elements assigned to
Division 1.1 unless the hazard is shown to correspond to one of the hazard categories in Appendix B.1, in which case the corresponding symbol, signal
word and/or the hazard statement shall be assigned
36
C.4.15 FLAMMABLE GASES
(CLASSIFIED IN ACCORDANCE with Appendix B.2)
Pictogram
Flame
Hazard category
Signal word
Hazard statement
1
Danger
Extremely flammable gas
Precautionary statements
Prevention
Keep away from heat/sparks/open
flames/hot surfaces. -No smoking.
Manufacturer, importer, or distributor to
specify applicable ignition source(s).
Response
Storage
Leaking gas fire:
Do not extinguish, unless leak can be
stopped safely.
Eliminate all ignition sources if safe to
do so.
37
Store in wellventilated place.
Disposal
C.4.15 FLAMMABLE GASES (CONTINUED)
(CLASSIFIED IN ACCORDANCE with Appendix B.2)
Pictogram
No Pictogram
Hazard category
Signal word
Hazard statement
2
Warning
Flammable gas
Precautionary statements
Prevention
Keep away from heat/sparks/open
flames/hot surfaces. -No smoking.
Manufacturer, importer, or distributor to
specify applicable ignition sources(s).
Response
Storage
Leaking gas fire: Do not extinguish,
unless leak can be stopped safely.
Eliminate all ignition sources if safe to
do so.
38
Store in wellventilated place.
Disposal
C.4.16 FLAMMABLE AEROSOLS
(CLASSIFIED IN ACCORDANCE with Appendix B.3)
Pictogram
Flame
Hazard category
Signal word
Hazard statement
1
Danger
Extremely flammable aerosol
2
Warning
Flammable aerosol
Precautionary statements
Prevention
Response
Storage
Keep away from heat/sparks/open
flames/hot surfaces. -No smoking.
Manufacturer, importer, or distributor to
specify applicable ignition sources(s).
Protect from sunlight.
Do not expose to
temperatures
exceeding
50 ºC/122 ºF.
Do not spray on an open flame or other
ignition source.
Pressurized container: Do not pierce or
burn, even after use.
39
Disposal
C.4.17 OXIDIZING GASES
(CLASSIFIED IN ACCORDANCE with Appendix B.4)
Pictogram
Flame over circle
Hazard category
Signal word
Hazard statement
1
Danger
May cause or intensify fire; oxidizer
Precautionary statements
Prevention
Keep/Store away from
clothing/…/combustible materials.
…Manufacturer, importer, or distributor
to specify other incompatible materials.
Response
Storage
In case of fire: Stop leak if safe to do so.
Keep reduction valves free from grease
and oil.
40
Store in wellventilated place.
Disposal
C.4.18 GASES UNDER PRESSURE
(CLASSIFIED IN ACCORDANCE with Appendix B.5)
Pictogram
Gas cylinder
Hazard category
Signal word
Hazard statement
Compressed gas
Warning
Contains gas under pressure; may explode if heated
Liquefied gas
Warning
Contains gas under pressure; may explode if heated
Dissolved gas
Warning
Contains gas under pressure; may explode if heated
Precautionary statements
Prevention
Response
Storage
Protect from sunlight.
Store in a wellventilated place.
41
Disposal
C.4.18 GASES UNDER PRESSURE (CONTINUED)
(CLASSIFIED IN ACCORDANCE with Appendix B.5)
Pictogram
Gas cylinder
Hazard category
Signal word
Hazard statement
Refrigerated liquefied gas
Warning
Contains refrigerated gas; may cause cryogenic burns or injury
Precautionary statements
Prevention
Wear cold insulating gloves/face
shield/eye protection.
Response
Storage
Thaw frosted parts with lukewarm
water. Do not rub affected area.
Get immediate medical
advice/attention
42
Store in wellventilated place.
Disposal
C.4.19 FLAMMABLE LIQUIDS
(CLASSIFIED IN ACCORDANCE with Appendix B.6)
Pictogram
Flame
Hazard category
1
2
3
Signal word
Danger
Danger
Warning
Hazard statement
Extremely flammable liquid and vapor
Highly flammable liquid and vapor
Flammable liquid and vapor
Precautionary statements
Prevention
Keep away from heat/sparks/open flames/hot surfaces.– No smoking.
Manufacturer, importer, or distributor to specify applicable ignition source(s).
Keep container tightly closed.
Ground/Bond container and receiving equipment
- if electrostatically sensitive material is for reloading.
- if product is volatile so as to generate hazardous atmosphere.
Response
Storage
Disposal
If on skin (or hair):
Remove/Take off
immediately all
contaminated clothing.
Rinse skin with
water/shower.
Store in a wellventilated place.
Keep cool.
Dispose of
contents/container to...
… in accordance with
local/regional/national/inter
national regulations (to be
specified).
In case of fire: Use ...
for extinction.
... Manufacturer,
importer, or distributor
to specify appropriate
media.
- if water increases
risk.
Use explosion-proof electrical/ventilating/
lighting/.../equipment.
... Manufacturer, importer, or distributor to specify other equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Wear protective gloves/eye protection/face protection
Manufacturer, importer, or distributor to specify type of equipment.
43
C.4.19 FLAMMABLE LIQUIDS (CONTINUED)
(CLASSIFIED IN ACCORDANCE with Appendix B.6)
Pictogram
No Pictogram
Hazard category
Signal word
Hazard statement
4
Warning
Combustible liquid
Precautionary statements
Prevention
Keep away from flames and hot
surfaces. – No smoking.
Wear protective gloves/eye
protection/face protection
Manufacturer, importer, or distributor to
specify type of equipment.
Response
Storage
In case of fire: Use ... for extinction.
... Manufacturer, importer, or distributor
to specify appropriate media.
if water increases risk.
44
Store in a wellventilated place. Keep
cool.
Disposal
Dispose of contents/container to...
in accordance with local/regional/
national/international regulations (to be
specified).
C.4.20 FLAMMABLE SOLIDS
(CLASSIFIED IN ACCORDANCE with Appendix B.7)
Pictogram
Flame
Hazard category
1
2
Signal word
Danger
Warning
Hazard statement
Flammable solid
Flammable solid
Precautionary statements
Prevention
Keep away from heat/sparks/open
flames/hot surfaces. - No smoking.
Manufacturer, importer, or distributor to
specify applicable ignition source(s).
Response
Storage
In case of fire: Use ... for extinction
... Manufacturer, importer, or distributor
to specify appropriate media.
if water increases risk.
Ground/Bond container and receiving
equipment.
- if electrostatically sensitive material
is for reloading.
Use explosion-proof
electrical/ventilating/ lighting/...
/equipment.
... Manufacturer, importer, or distributor
to specify other equipment.
- if dust clouds can occur.
Wear protective gloves/eye
protection/face protection
Manufacturer, importer, or distributor to
specify type of equipment.
45
Disposal
C.4.21 SELF-REACTIVE SUBSTANCES AND MIXTURES
(CLASSIFIED IN ACCORDANCE with Appendix B.8)
Pictogram
Exploding bomb
Hazard category
Type A
Signal word
Danger
Hazard statement
Heating may cause an explosion
Precautionary statements
Prevention
Response
Storage
Keep away from heat/sparks/open
flames/hot surfaces. - No smoking.
Manufacturer, importer, or distributor to
specify applicable ignition source(s).
In case of fire: Use ... for extinction
... Manufacturer, importer, or distributor
to specify appropriate media.
- if water increases risk.
Keep/Store away from
clothing/…/combustible materials.
... Manufacturer, importer, or distributor
to specify other incompatible materials.
In case of fire: Evacuate area. Fight
fire remotely due to the risk of
explosion.
Store in a wellventilated place. Keep
cool.
Store at temperatures
not exceeding
…°C/…°F.
... Manufacturer,
importer, or distributor
to specify temperature.
Keep only in original container.
Store away from other
materials.
Wear protective gloves/eye
protection/face protection.
Manufacturer, importer, or distributor to
specify type of equipment.
46
Disposal
Dispose of contents/container to...
… in accordance with
local/regional/national/international
regulations (to be specified).
C.4.21 SELF-REACTIVE substances and mixtures (CONTINUED)
(CLASSIFIED IN ACCORDANCE with Appendix B.8)
Pictograms
Exploding bomb and flame
Hazard category
Type B
Signal word
Danger
Hazard statement
Heating may cause a fire or explosion
Precautionary statements
Prevention
Response
Storage
Keep away from heat/sparks/open
flames/hot surfaces. - No smoking.
Manufacturer, importer, or distributor to
specify applicable ignition source(s).
In case of fire: Use ... for extinction.
... Manufacturer, importer, or distributor
to specify appropriate media.
- if water increases risk
Keep/Store away from
clothing/.../combustible materials.
... Manufacturer, importer, or distributor
to specify other incompatible materials.
In case of fire: Evacuate area. Fight
fire remotely due to the risk of
explosion.
Store in a wellventilated place. Keep
cool.
Store at temperatures
not exceeding
…°C/…°F.
... Manufacturer,
importer, or distributor
to specify temperature.
Keep only in original container.
Store away from other
materials.
Wear protective gloves/eye
protection/face protection.
Manufacturer, importer, or distributor to
specify type of equipment.
47
Disposal
Dispose of contents/container to...
…in accordance with
local/regional/national/international
regulations (to be specified).
C.4.21 SELF-REACTIVE substances and mixtures(CONTINUED)
(CLASSIFIED IN ACCORDANCE with Appendix B.8)
Pictogram
Flame
Hazard category
Type C
Type D
Type E
Type F
Signal word
Danger
Danger
Warning
Warning
Hazard statement
Heating may cause a fire
Heating may cause a fire
Heating may cause a fire
Heating may cause a fire
Precautionary statements
Prevention
Keep away from heat/sparks/open
flames/hot surfaces. - No smoking.
Manufacturer, importer, or distributor to
specify applicable ignition source(s).
Response
Storage
In case of fire: Use ... for extinction
... Manufacturer, importer, or distributor
to specify appropriate media.
- if water increases risk.
Store in a wellventilated place. Keep
cool.
Store at temperatures
not exceeding
…°C/…°F.
...Manufacturer,
importer, or distributor
to specify temperature.
Keep/Store away from
clothing/…/combustible materials.
…Manufacturer, importer, or distributor
to specify other incompatible materials.
Keep only in original container.
Store away from other
materials.
Wear protective gloves/eye
protection/face protection.
Manufacturer, importer, or distributor to
specify type of equipment.
48
Disposal
Dispose of contents/container to...
…in accordance with
local/regional/national/international
regulations (to be specified).
C.4.22 PYROPHORIC LIQUIDS
(CLASSIFIED IN ACCORDANCE with Appendix B.9)
Pictogram
Flame
Hazard category
1
Signal word
Danger
Hazard statement
Catches fire spontaneously if exposed to air
Precautionary statements
Prevention
Keep away from heat/sparks/open
flames/hot surfaces. - No smoking.
Manufacturer, importer, or distributor to
specify applicable ignition sources(s).
Do not allow contact with air.
Response
Storage
If on skin: Immerse in cool water/wrap
with wet bandages
Store contents under
...
... Manufacturer,
importer, or distributor
to specify appropriate
liquid or inert gas.
In case of fire: Use ... for extinction
... Manufacturer, importer, or distributor
to specify appropriate media.
- if water increases risk.
Wear protective gloves/eye
protection/face protection.
Manufacturer, importer, or distributor to
specify type of equipment.
49
Disposal
C.4.23 PYROPHORIC SOLIDS
(CLASSIFIED IN ACCORDANCE with Appendix B.10)
Pictogram
Flame
Hazard category
1
Signal word
Danger
Hazard statement
Catches fire spontaneously if exposed to air
Precautionary statements
Prevention
Keep away from heat/sparks/open
flames/hot surfaces. - No smoking.
Manufacturer, importer, or distributor to
specify applicable ignition source(s).
Do not allow contact with air.
Wear protective gloves/eye
protection/face protection
Manufacturer, importer, or distributor to
specify type of equipment.
Response
Storage
Brush off loose particles from skin.
Immerse in cool water/wrap in wet
bandages.
In case of fire: Use ... for extinction
... Manufacturer, importer, or distributor
to specify appropriate media.
- if water increases risk.
50
Store contents under
...
…Manufacturer,
importer, or distributor
to specify appropriate
liquid or inert gas.
Disposal
C.4.24 SELF-HEATING SUBSTANCES AND MIXTURES
(CLASSIFIED IN ACCORDANCE with appendix B.11)
Pictogram
Flame
Hazard category
1
2
Signal word
Danger
Warning
Hazard statement
Self-heating; may catch fire
Self-heating in large quantities; may catch fire
Precautionary statements
Prevention
Response
Storage
Keep cool. Protect from sunlight.
Maintain air gap
between stacks/pallets.
Wear protective gloves/eye
protection/face protection.
Manufacturer, importer, or distributor to
specify type of equipment.
Store bulk masses
greater than …
kg/…lbs at
temperatures not
exceeding …°C/…°F.
... Manufacturer,
importer, or distributor
to specify mass and
temperature.
Store away from other
materials.
51
Disposal
C. 4.25 substances and mixtures WHICH, IN CONTACT WITH WATER, EMIT FLAMMABLE GASES
(CLASSIFIED IN ACCORDANCE with appendix B.12)
Pictogram
Flame
Hazard category
1
Signal word
Danger
2
Danger
Hazard statement
In contact with water releases flammable gases, which may ignite
spontaneously
In contact with water releases flammable gas
Precautionary statements
Prevention
Response
Keep away from any possible contact
with water, because of violent reaction
and possible flash fire.
Brush off loose particles from skin and
immerse in cool water/wrap in wet
bandages.
Handle under inert gas. Protect from
moisture.
In case of fire: Use ... for extinction
... Manufacturer, importer, or distributor
to specify appropriate media.
- if water increases risk.
Wear protective gloves/eye
protection/face protection.
Manufacturer, importer, or distributor to
specify type of equipment.
Storage
52
Store in a dry place.
Store in a closed
container.
Disposal
Dispose of contents/container to...
…in accordance with
local/regional/national/ international
regulations (to be specified).
C. 4.25 substances and mixtures WHICH, IN CONTACT WITH WATER, EMIT FLAMMABLE GASES
(CONTINUED)
(CLASSIFIED IN ACCORDANCE with Appendix B.12)
Pictogram
Flame
Hazard category
3
Signal word
Warning
Hazard statement
In contact with water releases flammable gas
Precautionary statements
Prevention
Handle under inert gas. Protect
from moisture.
Wear protective gloves/eye
protection/face protection.
Manufacturer, importer, or distributor to
specify type of equipment.
Response
Storage
In case of fire: Use ... for extinction.
... Manufacturer, importer, or distributor
to specify appropriate media.
- if water increases risk.
53
Store in a dry place.
Store in a closed
container.
Disposal
Dispose of contents/container to...
... in accordance with
local/regional/national/international
regulations (to be specified).
C. 4.26 OXIDIZING LIQUIDS
(CLASSIFIED IN ACCORDANCE with appendix B.13)
Pictogram
Flame over circle
Hazard category
1
Signal word
Danger
Hazard statement
May cause fire or explosion; strong oxidizer
Precautionary statements
Prevention
Keep away from heat.
Keep/Store away from clothing and
other combustible materials.
Take any precaution to avoid mixing
with combustibles/...
... Manufacturer, importer, or distributor
to specify other incompatible materials.
Wear protective gloves /eye
protection/face protection.
Manufacturer, importer, or distributor to
specify type of equipment.
Response
Storage
If on clothing: Rinse immediately
contaminated clothing and skin with
plenty of water before removing
clothes.
In case of major fire and large
quantities: Evacuate area. Fight fire
remotely due to the risk of explosion.
In case of fire: Use ... for extinction.
... Manufacturer, importer, or distributor
to specify appropriate media.
- if water increases risk.
Wear fire/flame resistant/retardant
clothing.
54
Disposal
Dispose of contents/container to...
…in accordance with local/regional/
national/international regulations (to be
specified).
C. 4.26 OXIDIZING LIQUIDS (CONTINUED)
(CLASSIFIED IN ACCORDANCE with appendix B.13)
Pictogram
Flame over circle
Hazard category
2
3
Signal word
Danger
Warning
Hazard statement
May intensify fire; oxidizer
May intensify fire; oxidizer
Precautionary statements
Prevention
Keep away from heat.
Keep/Store away from
clothing/…/combustible materials.
…Manufacturer, importer, or distributor
to specify other incompatible materials.
Response
Storage
In case of fire: Use ... for extinction.
... Manufacturer, importer, or distributor
to specify appropriate media.
- if water increases risk.
Take any precaution to avoid mixing
with combustibles/...
... Manufacturer, importer, or distributor
to specify other incompatible materials.
Wear protective gloves/eye
protection/face protection.
Manufacturer, importer, or distributor to
specify type of equipment.
55
Disposal
Dispose of contents/container to...
…in accordance with local/regional/
national/international regulations (to be
specified).
C. 4.27 OXIDIZING SOLIDS
(CLASSIFIED IN ACCORDANCE with appendix B.14)
Pictogram
Flame over circle
Hazard category
1
Signal word
Danger
Hazard statement
May cause fire or explosion; strong oxidizer
Precautionary statements
Prevention
Keep away from heat.
Keep away from clothing and other
combustible materials.
Take any precaution to avoid mixing
with combustibles/...
…Manufacturer, importer, or distributor
to specify other incompatible materials.
Wear protective gloves/eye
protection/face protection.
Manufacturer, importer, or distributor to
specify type of equipment.
Response
Storage
If on clothing: Rinse immediately
contaminated clothing and skin with
plenty of water before removing
clothes.
In case of major fire and large
quantities: Evacuate area. Fight fire
remotely due to the risk of explosion.
In case of fire: Use ... for extinction.
... Manufacturer, importer, or distributor
to specify appropriate media.
- if water increases risk.
Wear fire/flame resistant/retardant
clothing.
56
Disposal
Dispose of contents/container to...
…in accordance with local/regional/
national/international regulations (to be
specified).
C.4.27 OXIDIZING SOLIDS (CONTINUED)
(CLASSIFIED IN ACCORDANCE with appendix B.14)
Pictogram
Flame over circle
Hazard category
Signal word
Hazard statement
2
Danger
May intensify fire; oxidizer
3
Warning
May intensify fire; oxidizer
Precautionary statements
Prevention
Keep away from heat.
Keep/Store away from clothing/…/
combustible materials.
… Manufacturer, importer, or distributor
to specify incompatible materials.
Response
Storage
In case of fire: Use ... for extinction.
... Manufacturer, importer, or distributor
to specify appropriate media.
- if water increases risk.
Take any precaution to avoid mixing
with combustibles/...
…Manufacturer, importer, or distributor
to specify other incompatible materials.
Wear protective gloves/eye
protection/face protection.
Manufacturer, importer, or distributor to
specify type of equipment.
57
Disposal
Dispose of contents/container to...
... in accordance with
local/regional/national/international
regulations (to be specified).
C. 4.28 ORGANIC PEROXIDES
(CLASSIFIED IN ACCORDANCE with appendix B.15)
Pictogram
Exploding bomb
Hazard category
Signal word
Hazard statement
Type A
Danger
Heating may cause an explosion
Precautionary statements
Prevention
Response
Storage
Keep away from heat/sparks/open
flames/hot surfaces.- No smoking.
Manufacturer, importer, or distributor to
specify applicable ignition source(s).
Store at temperatures
not exceeding
…°C/…°F. Keep cool.
... Manufacturer,
importer, or distributor
to specify temperature.
Keep/Store away from
clothing/…/combustible materials.
... Manufacturer, importer, or distributor
to specify incompatible materials.
Protect from sunlight.
Store away from other
materials.
Keep only in original container.
Wear protective gloves/eye
protection/face protection.
Manufacturer, importer, or distributor to
specify type of equipment.
58
Disposal
Dispose of contents/container to...
... in accordance with
local/regional/national/international
regulations (to be specified).
C. 4.28 ORGANIC PEROXIDES (CONTINUED)
(CLASSIFIED IN ACCORDANCE with appendix B.15)
Pictograms
Exploding bomb and flame
Hazard category
Signal word
Hazard statement
Type B
Danger
Heating may cause a fire or explosion
Precautionary statements
Prevention
Response
Storage
Keep away from heat/sparks/open
flames/hot surfaces. - No smoking.
Manufacturer, importer, or distributor to
specify applicable ignition source(s).
Store at temperatures
not exceeding
…°C/…°F. Keep cool.
Manufacturer, importer,
or distributor to specify
temperature.
Keep /Store away from
clothing/.../combustible materials.
... Manufacturer, importer, or distributor
to specify incompatible materials.
Protect from sunlight.
Store away from other
materials.
Keep only in original container.
Wear protective gloves/eye
protection/face protection.
Manufacturer, importer, or distributor to
specify type of equipment.
59
Disposal
Dispose of contents/container to...
... in accordance with
local/regional/national/international
regulations (to be specified).
C.4.28 ORGANIC PEROXIDES (CONTINUED)
(CLASSIFIED IN ACCORDANCE with appendix B.15)
Pictogram
Flame
Hazard category
Signal word
Hazard statement
Type C
Danger
Heating may cause a fire
Type D
Danger
Heating may cause a fire
Type E
Warning
Heating may cause a fire
Type F
Precautionary statements
Warning
Heating may cause a fire
Prevention
Response
Storage
Keep away from heat/sparks/open
flames/hot surfaces. - No smoking.
Manufacturer, importer, or distributor to
specify applicable ignition source(s).
Store at temperatures
not exceeding
…°C/…°F. Keep cool.
... Manufacturer,
importer, or distributor
to specify temperature.
Keep/Store away from clothing/.../
combustible materials
... Manufacturer, importer, or distributor
to specify incompatible materials.
Protect from sunlight.
Store away from other
materials.
Keep only in original container.
Wear protective gloves/eye
protection/face protection.
Manufacturer, importer, or distributor to
specify type of equipment.
60
Disposal
Dispose of contents/container to...
... in accordance with
local/regional/national/international
regulations (to be specified).
C.4.29 CORROSIVE TO METALS
(CLASSIFIED IN ACCORDANCE with appendix B.16)
Pictogram
Corrosion
Hazard category
Signal word
Hazard statement
1
Warning
May be corrosive to metals
Precautionary statements
Prevention
Keep only in original container.
Response
Storage
Absorb spillage to prevent material
damage.
61
Store in corrosive
resistant/... container
with a resistant inner
liner.
... Manufacturer,
importer, or distributor
to specify other
compatible materials.
Disposal
| File Type | application/pdf |
| Author | Adia's Computer |
| File Modified | 2009-09-03 |
| File Created | 2009-09-03 |